Trichlorogermane

Base Information

• Chemical Name: Trichlorogermane
• CAS No.: 1184-65-2
• Deprecated CAS: 1337469-58-5
• Molecular Formula: Cl3Ge H
• Molecular Weight: 179.957
• European Community (EC) Number: 214-673-5
• Wikidata: Q4463306
• Mol file: 1184-65-2.mol

Synonyms:Trichlorogermane;1184-65-2;Trichlorogermanium;Germane, trichloro-;EINECS 214-673-5;Q4463306

Chemical Property of Trichlorogermane

Chemical Property:

• Melting Point: -71°C
• Boiling Point: 75°C
• Flash Point: °C
• PSA: 0.00000
• Density: g/cm³
• LogP: 1.80020
• Water Solubility.: reac H2O [CRC10]
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 178.827736
• Heavy Atom Count: 4
• Complexity: 8

Purity/Quality:

98%,99%, ^*data from raw suppliers

Safty Information:

• Statements: 11-34
• Safety Statements: 16-26-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: Cl[Ge](Cl)Cl

Technology Process of Trichlorogermane

There total 12 articles about Trichlorogermane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

germanium dihydride dichloride (15230-48-5) → germanium (7440-56-4) + germane (7782-65-2) + germaniumtetrachloride (10038-98-9) + germanium(II) chloride + germanium hydride trichloride (1184-65-2)

Guidance literature:

byproducts: HCl, H2; decompn. at room temp.;;

Reference yield:

hydrogenchloride (7647-01-0,15364-23-5) + germanium (7440-56-4) → germaniumtetrachloride (10038-98-9) + germanium hydride trichloride (1184-65-2)

Guidance literature:

In neat (no solvent); treatment of finely divided germanium with HCl gas (400+/-20°C, quarz tube, 7 days); mixt. of products not separated;

DOI:10.1021/om00119a007

Reference yield:

hydrogenchloride (7647-01-0,15364-23-5) + Ge(x)Mg(1-x) → germane (7782-65-2) + germanium hydride trichloride (1184-65-2)

Guidance literature:

using diluted HCl (1 : 4);; passing the escaping gases through H2O (seperating HCl and HGeCl3); condensing with liquid air; fractionating with a Stock apparatus;;

DOI:10.1021/ja01668a015

upstream raw materials:

hydrogenchloride

germanium

germaniumtetrachloride

hypophosphorous acid

Downstream raw materials:

trimethyltin(IV)chloride

hydrogen

dimethyltin dichloride

methyltrichlorogermane