phenanthren-9-ylacetyl chloride

Base Information

• Chemical Name: phenanthren-9-ylacetyl chloride
• CAS No.: 98677-87-3
• Molecular Formula: C₁₆H₁₁ClO
• Molecular Weight: 254.716
• Mol file: 98677-87-3.mol

Synonyms:

Chemical Property of phenanthren-9-ylacetyl chloride

Chemical Property:

• Vapor Pressure: 1.12E-07mmHg at 25°C
• Boiling Point: 432.4°C at 760 mmHg
• Flash Point: 213.5°C
• Density: 1.28g/cm³

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of phenanthren-9-ylacetyl chloride

There total 5 articles about phenanthren-9-ylacetyl chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

9-phenanthrylacetic acid (25177-46-2) → 9-phenanthreneacetic acid chloride (98677-87-3)

Guidance literature:

With thionyl chloride; for 0.166667h; Heating;

DOI:10.1246/bcsj.56.3118

Reference yield:

9-methylphenanthrene (883-20-5) → 9-phenanthreneacetic acid chloride (98677-87-3)

Guidance literature:

Multi-step reaction with 4 steps

1: 92 percent / N-bromosuccinimide (NBS), benzoyl peroxide / CCl₄ / 1 h / Heating

2: 89 percent / ethanol; H₂O / 3 h / Heating

3: 93 percent / ethanol. KOH / 20 h / Heating

4: (COCl)2 / CH₂Cl₂ / 3 h / Ambient temperature

With potassium hydroxide; N-Bromosuccinimide; Perbenzoic acid; oxalyl dichloride; In tetrachloromethane; ethanol; dichloromethane; water;

DOI:10.1021/jo00223a046

Reference yield:

9-(cyanomethyl)phenanthrene (50781-52-7) → 9-phenanthreneacetic acid chloride (98677-87-3)

Guidance literature:

Multi-step reaction with 2 steps

1: 93 percent / ethanol. KOH / 20 h / Heating

2: (COCl)2 / CH₂Cl₂ / 3 h / Ambient temperature

With potassium hydroxide; oxalyl dichloride; In dichloromethane;

DOI:10.1021/jo00223a046

upstream raw materials:

9-phenanthrylacetic acid

9-methylphenanthrene

9-(cyanomethyl)phenanthrene

9-bromomethylphenantrene

Downstream raw materials:

4-hydroxy-4-(1-propenyl)-4,5-dihydroacephenanthrylene

4-hydroxy-4-(2-propenyl)-4,5-dihydroacephenanthrylene

4-hydroxy-4,5-dihydroacephenanthrylene

4-(2-propenyl)acephenanthrylene