25177-46-2Relevant articles and documents
Phenanthrylalkonoic acids, II: Syntheses and antiinflammatory activity of 2-, 3- and 9-phenanthryl- and 9-chloro-3-phenanthrylacetic acids
Fernandez,Gomez,Lopez,Santos,Calleja,Cano,Lopez-Suarez
, p. 331 - 335 (1988)
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Southwick et al.
, p. 1358,1359, 1366 (1961)
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Preparation method of acid with different substituent groups
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Paragraph 0093-0097, (2019/10/23)
The invention discloses a preparation method of an acid with different substituent groups. A terminal alkyne is lithiated with n-butyllithium, and then reacts with isopropoxyboronic acid pinacol ester, hydrogen chloride is added to achieve quenching, then the obtained reaction product is oxidized by an oxidizing agent, and the oxidized reaction product is separated and purified to obtain the acid.The method of the invention has the advantages of simplicity in operation, one-pot process preparation, no metal catalysis, nontoxic reagents, greenness, environmental friendliness and high atomic utilization rate, and provides a novel and quick way for preparing the acid with different substituent groups; and the obtained acid is an important fine chemical product, and can be widely used in fields of medicines, pesticides, spices and other industries.
Reductive removal of phenylseleno groups from α-phenylseleno carbonyl compounds by means of tellurolate anions
Silveira,Lenardao,Comasseto
, p. 575 - 582 (2007/10/02)
α-Phenylseleno carbonyl compounds are reduced to the corresponding selenium free carbonyl compounds by reaction with organic and inorganic tellurolate anions.