Technology Process of methylcyclohexane, titanium, toluene
There total 4 articles about methylcyclohexane, titanium, toluene which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
toluene; K{BEt3H};
In
neat (no solvent);
Sonication; soln. of TiCl4 treated with a soln. of K(BEt3H) at room temp. over a period of 1 h under sonication, sonication for a further hour; pptn. filtered off, extd. with benzene for 3 times, clear filtrates combined, solvent evapd. to dryness in vacuo, pentane added, filtered, pentane removed in vacuo, recrystd. from pentane, elem. anal.;
- Guidance literature:
-
With
K(BEt3H);
In
toluene;
Sonication; TiCl4 under Ar dissolved in toluene is immersed in an ultrasonic bath for 60 min at room temp., addn. of K(BEt3H) in toluene, for 60 min in the ultrasonic bath; filtn. of the ppt., washing (benzene), removal the solvent of the filtrate, dissolving the residue in pentane, filtn., removal the pentane, recrystn. of the residue (pentane), elem. anal.;
DOI:10.1016/0304-5102(92)80250-K
- Guidance literature:
-
With
potassium;
In
tetrahydrofuran;
TiCl3(THF)3 dissolved in THF and toluene at room temp., cooled on bath at -110°C and evacuated (<1E-5 Pa), potassium vapour condensed into soln. for 50 min, flask rotated for 15 min at -100°C; evapd., solid taken up in THF, filtered through glass wool and Al2O3 (Brockmann Activity II), evapd. in vac., recrystd. from pentane; elem. anal.;
DOI:10.1039/DT9830001123
