Plumbum iodatum

Base Information

• Chemical Name: Plumbum iodatum
• CAS No.: 10101-63-0
• Molecular Formula: I₂Pb
• Molecular Weight: 465.2
• Hs Code.: 28276000
• UNII: OTL90F2GLT
• DSSTox Substance ID: DTXSID101014310
• Nikkaji Number: J43.836G
• Mol file: 10101-63-0.mol

Synonyms:Lead(II)iodide;LEADIODIDE;PLUMBUM IODATUM;LEAD IODIDE [MI];LEAD IODIDE [HSDB];LEAD IODIDE [WHO-DD];PLUMBUM IODATUM [HPUS];DTXSID101014310;AKOS030228135;L0279

Chemical Property of Plumbum iodatum

Chemical Property:

• Appearance/Colour: Golden yellow powder
• Melting Point: 402 °C(lit.)
• Boiling Point: 127 °C at 760 mmHg
• Flash Point: 954°C
• PSA: 0.00000
• Density: 6.16 g/mL at 25 °C(lit.)
• LogP: 1.39060
• Storage Temp.: Keep in dark place,Inert atmosphere,Room temperature
• Sensitive.: Light Sensitive
• Solubility.: Soluble in concentrated solutions of alkali iodides and sodium t
• Water Solubility.: Partially soluble in water. Freely soluble in sodium thiosulfate solution. Soluble in concentrated solutions of alkali iodides.
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 0
• Exact Mass: 461.78560
• Heavy Atom Count: 3
• Complexity: 0

Purity/Quality:

99.99%, ^*data from raw suppliers

Lead(II) iodide ^*data from reagent suppliers

Safty Information:

• Pictogram(s): T, N
• Hazard Codes: T,N
• Statements: 61-20/22-33-50/53-62
• Safety Statements: 53-45-60-61

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: [I-].[I-].[Pb+2]
• Description: Lead (II) iodide (chemical formula: PbI) is a kind of inorganic salt. It appears as a bright yellow crystalline solid. It has some special applications such as the manufacture of solar cells, X-rays, and gamma-ray detectors. In addition, it can also be used as a paint pigment for being used in art for bronzing and in gold-like mosaic tiles. It can be commonly synthesized through a double displacement reaction between potassium iodide KI and lead (II) nitrate Pb(NO3)2 in water solution. Lead (II) acetate and sodium iodide can also be used as the substitute of lead nitrate and potassium iodide, respectively. Alternatively, it can be manufactured through the reaction between iodine vapor and the molten lead. It is also used in printing and photography. However, it is hazard to the environment, and should be taken care of to limit spread to the environment.
• Physical properties: Yellow hexagonal crystals; density 6.16 g/cm3; melts at 402°C; vaporizes at 954°C; decomposes at 180°C when exposed to green light; slightly soluble in water (0.44 g/L at 0°C and 0.63 g/L at 20°C); Ksp 8.49x10-9 at 25°C; partially soluble in boiling water (4.1 g/L at 100°C); insoluble in ethanol; soluble in alkalis and alkali metal iodide solutions.
• Uses: Lead(II) iodide is used as a detector material for high energy photons including x-rays and gamma rays. It is used in photography, printing, mosaic gold, and bronzing. It exhibits ferroelastic properties and has efficiency in stopping X-ray and gamma ray, which provides excellent environmental stability. Used in bronzing, printing, photography, and mosaic gold Bronzing, gold pencils, mosaic gold, printing, photography.

Technology Process of Plumbum iodatum

There total 187 articles about Plumbum iodatum which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

triphenylpropylplumbane (74086-81-0) → iodobenzene (591-50-4) + 1-iodo-propane (107-08-4) + lead(II) iodide (10101-63-0)

Guidance literature:

With I₂; In chloroform-d1; (N2), stirred, treated with 3 equiv I2 at 0°C; filtered; NMR, iodobenzene : 1-iodopropane = 3:1;

DOI:10.1021/om00054a069

Reference yield: 93.0%

3-butenyltriphenylplumbane (134879-52-0) → iodobenzene (591-50-4) + 4-iodobut-1-ene (7766-51-0) + lead(II) iodide (10101-63-0)

Guidance literature:

With I₂; In chloroform-d1; (N2), stirred, treated with 3 equiv I2 at 25°C; filtered; NMR, IR, mass. spectra;

DOI:10.1021/om00054a069

Reference yield: 90.0%

1,3-propanediylbis{triphenylplumbane} (134879-53-1) → iodobenzene (591-50-4) + 1,3-Diiodopropane (627-31-6) + lead(II) iodide (10101-63-0)

Guidance literature:

With I₂; In chloroform-d1; (N2), stirred, treated with 6 equiv I2 at 25°C; filtered; NMR, IR, mass. spectra;

DOI:10.1021/om00054a069

upstream raw materials:

iodine

lead acetate

potassium iodide

lead

Downstream raw materials:

lead(II) chloride

CsI3Pb, black

lead⁽²⁺⁾ cation

iodide

Refernces

• 1、 Hao, Feng,Stoumpos, Constantinos C.,Liu, Zhao,Chang, Robert P. H.,Kanatzidis, Mercouri G.. "Controllable perovskite crystallization at a gas-solid interface for hole conductor-free solar cells with steady power conversion efficiency over 10%". . p. 16411 - 16419. Retrieved 2014.
• 2、 Ziegler, M.. "". . p. 1 - 4. Retrieved 1961.
• 3、 Dimitrovska-Lazova, Sandra,Bukleski, Miha,Tzvetkov, Peter,Aleksovska, Slobotka,Kovacheva, Daniela. "Crystal structure of the high-temperature polymorph of C(NH2)3PbI3 and its thermal decomposition". . . Retrieved 2021.
• 4、 Saito, Shingo,Goto, Takenari. "Spatial-confinement effect on phonons and excitons in PbI2 microcrystallites". . . Retrieved 1995.
• 5、 Huang, Baojun,He, Qin,Fa, Wenjun,Li, Pinjiang,Zhang, Yange,Zheng, Zhi. "Rapid sonochemical preparation of shape-selective lead iodide". . p. 2599 - 2604. Retrieved 2012.
• 6、 Nikolenko,Brichkin,Razumov. "Dye J-aggregate-semiconductor nanocrystal hybrid nanostructures in reverse micelles: An experimental study". . p. 1196 - 1202. Retrieved 2011.
• 7、 Iguchi, Hiroaki,Kitao, Shinji,Seto, Makoto,Takaishi, Shinya,Yamashita, Masahiro. "Predominance of covalency in water-vapor-responsive MMX-type chain complexes revealed by 129I Moessbauer spectroscopy". . p. 8767 - 8773. Retrieved 2014.
• 8、 Aslani, Alireza,Morsali, Ali. "Sonochemical synthesis of nano-sized metal-organic lead(II) polymer: A precursor for the preparation of nano-structured lead(II) iodide and lead(II) oxide". . p. 5012 - 5016. Retrieved 2009.
• 9、 Casamajor, P.. "-". . p. 132 - 134. Retrieved 1885.
• 10、 Yang, Shuang,Zheng, Yi Chu,Hou, Yu,Chen, Xiao,Chen, Ying,Wang, Yun,Zhao, Huijun,Yang, Hua Gui. "Formation mechanism of freestanding CH3NH3PbI3 functional crystals: In situ transformation vs dissolution-crystallization". . p. 6705 - 6710. Retrieved 2014.