(Z)-Hex-2-enyl acetate

Base Information

• Chemical Name: (Z)-Hex-2-enyl acetate
• CAS No.: 56922-75-9
• Molecular Formula: C8H14 O2
• Molecular Weight: 142.198
• European Community (EC) Number: 260-440-6
• UNII: PT792BQ57D
• DSSTox Substance ID: DTXSID501314752
• Nikkaji Number: J118.138F
• Wikidata: Q27286735
• RXCUI: 2274706
• Mol file: 56922-75-9.mol

Synonyms:(Z)-Hex-2-enyl acetate;[(Z)-hex-2-enyl] acetate;56922-75-9;2-Hexen-1-ol, acetate, (Z)-;Hexenyl acetate, (2Z)-;cis-2-hexenyl acetate;(2Z)-hexenyl acetate;(Z)-2-Hexenyl acetate;UNII-PT792BQ57D;PT792BQ57D;EINECS 260-440-6;AI3-34798;BRN 1721851;trans-2-hexen-1-yl acetate;2-Hexen-1-yl acetate, trans-;2-Hexen-1-ol, acetate, (2E)-;EINECS 219-680-7;AI3-34393;trans - hex - 2 - enyl acetate;2-hexen-1-ol, 1-acetato, (2e)-;Hex-trans-2-enyl acetate;(2Z)-2-Hexenyl acetate;(Z)-1-Acetoxy-2-hexene;cis-2-Hexen-1-ol, acetate;(Z)-2-Hexen-1-ol acetate;SCHEMBL891744;HRHOWZHRCRZVCU-WAYWQWQTSA-N;DTXSID501314752;CAA49718;2-Hexen-1-ol, acetate, (2Z)-;(Z)-2-HEXEN-1-YL ACETATE;2-HEXENYL ACETATE, (2Z)-;LS-2804;2-HEXEN-1-OL, 1-ACETATE, (2Z)-;Q27286735

Chemical Property of (Z)-Hex-2-enyl acetate

Chemical Property:

• Boiling Point: 85-90 °C(Press: 70 Torr)
• PSA: 26.30000
• Density: 0.901±0.06 g/cm3(Predicted)
• LogP: 1.90580
• XLogP3: 2
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 5
• Exact Mass: 142.099379685
• Heavy Atom Count: 10
• Complexity: 116

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCC=CCOC(=O)C
• Isomeric SMILES: CCC/C=C\COC(=O)C

Technology Process of (Z)-Hex-2-enyl acetate

There total 16 articles about (Z)-Hex-2-enyl acetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

1-hexene (592-41-6,25067-06-5) + palladium diacetate (3375-31-3) → 2-hexenyl acetate (2497-18-9,56922-75-9,10094-40-3) + acetic acid hex-3-enyl ester (3681-82-1,1708-82-3)

Guidance literature:

With p-benzoquinone; bis(triphenylphosphoranylidene)-ammonium acetate; In chloroform;

DOI:10.1016/S0022-328X(99)00521-5

Reference yield: 59.0%

1-hexene (592-41-6,25067-06-5) + tetraethylammonium acetate (1185-59-7) → 2-hexenyl acetate (2497-18-9,56922-75-9,10094-40-3) + acetic acid hex-3-enyl ester (3681-82-1,1708-82-3) + hex-4-en-3-ol acetate

Guidance literature:

With palladium diacetate; p-benzoquinone; In chloroform; at 20 ℃; Further Variations:; Reagents; Product distribution;

DOI:10.1016/S0022-328X(01)00825-7

Reference yield:

2-hexen-1-ol (2305-21-7) → 2-hexenyl acetate (2497-18-9,56922-75-9,10094-40-3) + 2-hexenal (505-57-7)

Guidance literature:

With oxygen; In acetic acid; at 60 ℃; for 5h; Title compound not separated from byproducts.;

DOI:10.1039/b207098g

upstream raw materials:

1-bromo-2-hexene

sodium acetate

1-hexene

acetic acid

Downstream raw materials:

(E)-1-(hex-2-en-1-yl)-4-methoxybenzene

(E)-methyl 4-(hex-2-en-1-yl)benzoate

(S,E)-methyl 2-(N-ethyl-N-(4-methoxyphenyl)amino)-2-phenyloct-4-enoate

(2E)-hex-2-en-1-ylbenzene