lithium oxidoazanide

Base Information

• Chemical Name: lithium oxidoazanide
• CAS No.: 36529-65-4
• Molecular Formula: HLiNO-
• Molecular Weight: 36.9471
• Mol file: 36529-65-4.mol

Synonyms:

Chemical Property of lithium oxidoazanide

Chemical Property:

• Vapor Pressure: 179mmHg at 25°C
• Boiling Point: 56.5°C at 760 mmHg

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of lithium oxidoazanide

There total 3 articles about lithium oxidoazanide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

piloty's acid (599-71-3) + phenyllithium (591-51-5) → lithium oxonitrite (36529-65-4) + lithium benzenesulfinate (16883-74-2) + benzene (71-43-2,26181-88-4,54682-86-9,13967-78-7,174973-66-1)

Guidance literature:

In diethyl ether; at -196.16 - 19.84 ℃; Schlenk technique; Inert atmosphere;

DOI:10.1016/j.jinorgbio.2012.09.022

Reference yield:

N-oxo-N-nitrosoamine (16824-89-8,12533-50-5) + lithium (7439-93-2) → hyponitrite dianion (57932-55-5,57932-56-6) + NNO2(1-) + cis-(NO)2(1-) + N(Li)O (36529-65-4) + Nitrite

Guidance literature:

In solid matrix; Irradiation (UV/VIS); UV irradiation of a rigid 7 K argon matrix contaning Li atoms and (NO)2;further products; detected by IR spectra;

DOI:10.1021/ja0029331

Reference yield:

N-oxo-N-nitrosoamine (16824-89-8,12533-50-5) + argon + lithium (7439-93-2) → gauche-nitric oxide dimer cation + trans-hyponitrite + Li(NO)Li + Li(1+)*Ar*(NO)2(2-)*Ar*Li(1+)=Li(Ar)(NO)2Ar(Li) + N(Li)O (36529-65-4)

Guidance literature:

In solid matrix; Irradiation (UV/VIS); UV irradiation of a rigid 7 K argon matrix contaning Li atoms and (NO)2;further products; detected by IR spectra;

DOI:10.1021/ja0029331

upstream raw materials:

piloty's acid

phenyllithium

N-oxo-N-nitrosoamine

lithium