Mercury(1+)

Base Information

• Chemical Name: Mercury(1+)
• CAS No.: 22542-11-6
• Molecular Formula: Hg
• Molecular Weight: 200.59
• DSSTox Substance ID: DTXSID50177074
• Wikidata: Q83047387
• Mol file: 22542-11-6.mol

Synonyms:Mercury, ion (Hg1+);UNII-0QU1O5HV9Z;Calomel (mercurous chloride);DTXSID50177074

Chemical Property of Mercury(1+)

Chemical Property:

• PSA: 0.00000
• LogP: -0.00250
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 201.970644
• Heavy Atom Count: 1
• Complexity: 0

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: [Hg+]

Technology Process of Mercury(1+)

There total 8 articles about Mercury(1+) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

bis(triethylgermyl)mercury (4149-28-4) → germanium (7440-56-4) + germanium ion + pyrographite (7440-44-0) + mercury + mercury(1+) (22542-11-6)

Guidance literature:

In gaseous matrix; Electric Arc; feeding He/(GeEt3)2Hg mixt. into flash electric discharge flow-type cell (quartz windows, tungsten electrodes, p(He)=133-1330 Pa, p((GeEt3)2Hg)=1.33-133 Pa, condensors battery charged to 20 kV, pulse (several A for 0.2 μs); further products; emission UV spectroscopy;

Reference yield:

mercury → mercury(1+) (22542-11-6)

Guidance literature:

With rac-cysteine; In not given; Electrochem. Process; observation of anodic behavior of cysteine on Hg dropping electrode;; very small amt. of Hg(1+) in soln.;;

DOI:10.1021/ja01868a048

Reference yield:

dimercury(2+) (12596-26-8) → mercury(1+) (22542-11-6)

Guidance literature:

In water; equil. constant given;;

DOI:10.1021/ja01849a003

upstream raw materials:

dimercury⁽²⁺⁾

helium ion

mercury ion

bis(triethylgermyl)mercury

Downstream raw materials:

tris(2,2'-bipyridine)iron(II)⁽²⁺⁾

mercury ion

manganese(II)

cerium(III) ion