Tricyclo[12.3.1.12,6]nonadeca-1(18),2,4,6(19),10,- 14,16-heptaen-9-one,3,17-dihydroxy-,(10E)-

Base Information

Chemical Name:Tricyclo[12.3.1.12,6]nonadeca-1(18),2,4,6(19),10,- 14,16-heptaen-9-one,3,17-dihydroxy-,(10E)-
CAS No.:52330-11-7
Molecular Formula:C19H18O3
Molecular Weight:294.34
Hs Code.:
Mol file:52330-11-7.mol

Synonyms:ALNUSONE;

Suppliers and Price of Tricyclo[12.3.1.12,6]nonadeca-1(18),2,4,6(19),10,- 14,16-heptaen-9-one,3,17-dihydroxy-,(10E)-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Total 10 raw suppliers

Chemical Property of Tricyclo[12.3.1.12,6]nonadeca-1(18),2,4,6(19),10,- 14,16-heptaen-9-one,3,17-dihydroxy-,(10E)-

Chemical Property:

PSA：57.53000
LogP:3.76890

Purity/Quality:: Analysis control,97.5% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of Tricyclo[12.3.1.12,6]nonadeca-1(18),2,4,6(19),10,- 14,16-heptaen-9-one,3,17-dihydroxy-,(10E)-

There total 11 articles about Tricyclo[12.3.1.12,6]nonadeca-1(18),2,4,6(19),10,- 14,16-heptaen-9-one,3,17-dihydroxy-,(10E)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

: 79422-51-8
bis(O-methoxymethyl)alnusone

: 52330-11-7
alnusone

Guidance literature:: With sulfuric acid; In acetic acid; for 0.2h; Heating;
DOI:10.1021/ja00411a034

Reference yield:

: 155997-96-9
3-<4-(methoxymethoxy)phenyl>propionic acid

: 52330-11-7
alnusone

Guidance literature:: Multi-step reaction with 10 steps

1: lithium aluminum hydride / diethyl ether / 1.) 0 deg C, 0.5 h, 2.) 25 deg C, 5 h

2: chromium trioxide, pyridine / CH₂Cl₂ / 0.17 h / 25 °C

3: boron trifluoride etherate / CH₂Cl₂ / 1.) 0 deg C, 0.5 h, 2.) 25 deg C, 1.5 h

4: 1.) n-butyllithium / tetrahydrofuran; diethyl ether / 1.) -30 deg C, 1.5 h, 2.) 0 deg C, 12 h

5: yellow mercuric oxide, mercuric chloride, water / methanol / 18 h / Heating

6: pyridine / 12 h / 25 °C

7: diazabicyclononane / CHCl₃ / 0.5 h / 25 °C

8: silver trifluoroacetate, iodine / CHCl₃ / 0.75 h

9: 46 percent / tetrakis(triphenylphosphine)nickel⁽⁰⁾ / dimethylformamide / 1.) 25 deg C, 20 min, 2.) 50 deg C, 40 h

10: 72 percent / aq. sulfuric acid / acetic acid / 0.2 h / Heating

With pyridine; chromium(VI) oxide; lithium aluminium tetrahydride; n-butyllithium; tetrakis(triphenylphosphine)nickel⁽⁰⁾; diazabicyclononane; sulfuric acid; boron trifluoride diethyl etherate; water; iodine; silver trifluoroacetate; mercury dichloride; mercury(II) oxide; In tetrahydrofuran; pyridine; methanol; diethyl ether; dichloromethane; chloroform; acetic acid; N,N-dimethyl-formamide;
DOI:10.1021/ja00411a034

Reference yield:

: 74882-15-8
3-(4-methoxymethoxyphenyl)propyl alcohol

: 52330-11-7
alnusone

Guidance literature:: Multi-step reaction with 9 steps

1: chromium trioxide, pyridine / CH₂Cl₂ / 0.17 h / 25 °C

2: boron trifluoride etherate / CH₂Cl₂ / 1.) 0 deg C, 0.5 h, 2.) 25 deg C, 1.5 h

3: 1.) n-butyllithium / tetrahydrofuran; diethyl ether / 1.) -30 deg C, 1.5 h, 2.) 0 deg C, 12 h

4: yellow mercuric oxide, mercuric chloride, water / methanol / 18 h / Heating

5: pyridine / 12 h / 25 °C

6: diazabicyclononane / CHCl₃ / 0.5 h / 25 °C

7: silver trifluoroacetate, iodine / CHCl₃ / 0.75 h

8: 46 percent / tetrakis(triphenylphosphine)nickel⁽⁰⁾ / dimethylformamide / 1.) 25 deg C, 20 min, 2.) 50 deg C, 40 h

9: 72 percent / aq. sulfuric acid / acetic acid / 0.2 h / Heating

With pyridine; chromium(VI) oxide; n-butyllithium; tetrakis(triphenylphosphine)nickel⁽⁰⁾; diazabicyclononane; sulfuric acid; boron trifluoride diethyl etherate; water; iodine; silver trifluoroacetate; mercury dichloride; mercury(II) oxide; In tetrahydrofuran; pyridine; methanol; diethyl ether; dichloromethane; chloroform; acetic acid; N,N-dimethyl-formamide;
DOI:10.1021/ja00411a034