Bis(pentafluoropropionyl) peroxide

Base Information

• Chemical Name: Bis(pentafluoropropionyl) peroxide
• CAS No.: 356-45-6
• Molecular Formula: C6F10 O4
• Molecular Weight: 326.048
• Hs Code.: 2915900090
• European Community (EC) Number: 206-605-8
• UNII: 5A3C39G3TI
• DSSTox Substance ID: DTXSID4059883
• Nikkaji Number: J193.851G
• Wikidata: Q27261733
• Mol file: 356-45-6.mol

Synonyms:Bis(pentafluoropropionyl) peroxide;356-45-6;Peroxide, bis(pentafluoropropionyl);perfluoropropionyl peroxide;2,2,3,3,3-pentafluoropropanoyl 2,2,3,3,3-pentafluoropropaneperoxoate;UNII-5A3C39G3TI;Peroxide, bis(2,2,3,3,3-pentafluoro-1-oxopropyl);5A3C39G3TI;EINECS 206-605-8;perfluorodipropionyl peroxide;BIS-(PENTAFLUOROPROPIONYL) PEROXIDE;SCHEMBL426585;bis(perfluoropropionyl) peroxide;DTXSID4059883;bis(pentafluoropropanoyl) peroxide;C6F10O4;Bis-(pentafluoropropionyl)peroxide;C6-F10-O4;Q27261733

Chemical Property of Bis(pentafluoropropionyl) peroxide

Chemical Property:

• Vapor Pressure: 43.3mmHg at 25°C
• Boiling Point: 96.6°Cat760mmHg
• Flash Point: 13°C
• PSA: 52.60000
• Density: 1.723g/cm³
• LogP: 2.38300
• XLogP3: 3.8
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 14
• Rotatable Bond Count: 5
• Exact Mass: 325.96369010
• Heavy Atom Count: 20
• Complexity: 356

Purity/Quality:

98%,99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C(=O)(C(C(F)(F)F)(F)F)OOC(=O)C(C(F)(F)F)(F)F

Technology Process of Bis(pentafluoropropionyl) peroxide

There total 6 articles about Bis(pentafluoropropionyl) peroxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 3.0%

perfluoropropylene (116-15-4,13429-24-8,25120-07-4,6792-31-0) → Hexafluoropropene oxide (428-59-1,25038-02-2) + bis(pentafluoropropionyl)peroxide (356-45-6)

Guidance literature:

With potassium hydroxide; dihydrogen peroxide; In methanol; at -37 ℃; for 0.333333h;

Reference yield:

2,2,3,3,3-pentafluoropropanoic anhydride (356-42-3) → pentafluoropropionic acid (422-64-0) + bis(pentafluoropropionyl)peroxide (356-45-6)

Guidance literature:

With dihydrogen peroxide; Potassium pentafluoropropionate; at 0 ℃; for 0.166667h;

DOI:10.1021/ol016338v

Reference yield:

perfluoropropylene (116-15-4,13429-24-8,25120-07-4,6792-31-0) → Hexafluoropropene oxide (428-59-1,25038-02-2) + bis(pentafluoropropionyl)peroxide (356-45-6) + trifluoroacetic acid (76-05-1)

Guidance literature:

With potassium hydroxide; dihydrogen peroxide; In methanol; water; at -37 ℃; Product distribution; Mechanism; molar ratio of H₂O₂:HFP and of KOH:HFP;;

upstream raw materials:

perfluoropropylene

2,2,3,3,3-pentafluoropropanoic anhydride

perfluoropropanoyl fluoride

Downstream raw materials:

2,2-dinitropropane

acetone

sodium pentafluoropropionate

butanone

Refernces

• 1、 Valverde, Elena,Kawamura, Shintaro,Sekine, Daisuke,Sodeoka, Mikiko. "Metal-free alkene oxy- and amino-perfluoroalkylations: Via carbocation formation by using perfluoro acid anhydrides: Unique reactivity between styrenes and perfluoro diacyl peroxides". . p. 7115 - 7121. Retrieved 2018/09/25.
• 2、 Sansotera, Maurizio,Gambarotti, Cristian,Famulari, Antonino,Baggioli, Alberto,Soave, Raffaella,Venturini, Francesco,Meille, Stefano V.,Wlassics, Ivan,Navarrini, Walter. "Free-radical selective functionalization of 1,4-naphthoquinones by perfluorodiacyl peroxides". . p. 5298 - 5309. Retrieved 2014/12/10.