3-(Methoxycarbonyl)-7-oxabicyclo[2.2.1]heptane-2-carboxylic acid

Base Information

Chemical Name:3-(Methoxycarbonyl)-7-oxabicyclo[2.2.1]heptane-2-carboxylic acid
CAS No.:57105-58-5
Molecular Formula:C9H12O5
Molecular Weight:200.191
Hs Code.:
DSSTox Substance ID:DTXSID40972575
Nikkaji Number:J59.419I
Mol file:57105-58-5.mol

Synonyms:57105-58-5;3-(methoxycarbonyl)-7-oxabicyclo[2.2.1]heptane-2-carboxylic acid;Endothal-monomethyl;Methyl hydrogen 3,6-endoxohexahydrophthalate;3-methoxycarbonyl-7-oxabicyclo[2.2.1]heptane-2-carboxylic acid;Methyl 7-oxabicyclo(2.2.1)heptane-2,3-dicarboxylate;7-Oxabicyclo(2.2.1)heptane-2,3-dicarboxylic acid, monomethyl ester;7-Oxabicyclo[2.2.1]heptane-2,3-dicarboxylic acid, monomethyl ester;SCHEMBL2332679;DTXSID40972575;RTYHOZSKZMLUKB-UHFFFAOYSA-N;AKOS027196595;LS-98751;EN300-222627;Z1508928884;3-(methoxycarbonyl)-7-oxabicyclo[2.2.1]heptane-2-carboxylicacid;7-Oxa-bicyclo[2,2,1]heptane-2,3-dicarboxylic acid monomethyl ester;7-Oxa-bicyclo [2,2,1]heptane-2,3-dicarboxylic acid monomethyl ester;7-Oxabicyclo[2.2.1]heptane-2,3-dicarboxylic acid hydrogen 2-methyl ester

Suppliers and Price of 3-(Methoxycarbonyl)-7-oxabicyclo[2.2.1]heptane-2-carboxylic acid

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 2 raw suppliers

Chemical Property of 3-(Methoxycarbonyl)-7-oxabicyclo[2.2.1]heptane-2-carboxylic acid

Chemical Property:

Vapor Pressure:1.7E-05mmHg at 25°C
Boiling Point:339.4°C at 760 mmHg
Flash Point:137.1°C
PSA：72.83000
Density:1.37g/cm³
LogP:0.03760
XLogP3:-0.1
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:5
Rotatable Bond Count:3
Exact Mass:200.06847348
Heavy Atom Count:14
Complexity:274

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:COC(=O)C1C2CCC(C1C(=O)O)O2

Technology Process of 3-(Methoxycarbonyl)-7-oxabicyclo[2.2.1]heptane-2-carboxylic acid

There total 4 articles about 3-(Methoxycarbonyl)-7-oxabicyclo[2.2.1]heptane-2-carboxylic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 6118-51-0
exo-3,6-epoxy-1,2,3,6-tetrahydrophthalic anhydride

: 67-56-1
methanol

: 57105-58-5,79315-91-6,104485-83-8,104485-84-9,112918-08-8,121423-53-8,130464-50-5,130464-52-7,135029-26-4
7-oxabicyclo[2.2.1]heptane-2,3-dicarboxylic acid monomethyl ester

Guidance literature:: With palladium 10% on activated carbon; hydrogen; at 50 ℃; under 37503.8 Torr;
DOI:10.2174/157018011795906730

Reference yield: 48.0%

: 6118-51-0
exo-3,6-epoxy-1,2,3,6-tetrahydrophthalic anhydride

: 67-56-1
methanol

: 57105-58-5
7-oxabicyclo[2.2.1]heptane-2,3-dicarboxylic acid monomethyl ester

Guidance literature:: With hydrogen; palladium on activated charcoal; for 17h; under 3040 Torr;
DOI:10.1016/S0045-2068(02)00524-2

Reference yield:

: 6118-51-0
exo-3,6-epoxy-1,2,3,6-tetrahydrophthalic anhydride

: 57105-58-5,79315-91-6,104485-83-8,104485-84-9,112918-08-8,121423-53-8,130464-50-5,130464-52-7,135029-26-4
7-oxabicyclo[2.2.1]heptane-2,3-dicarboxylic acid monomethyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: H₂ / Pd/C

2: Heating

With hydrogen; palladium on activated charcoal;
DOI:10.1021/ol0003735