baimuxinol

Base Information

• Chemical Name: baimuxinol
• CAS No.: 105013-72-7
• Molecular Formula: C₁₅H₂₆O₂
• Molecular Weight: 238.37
• Mol file: 105013-72-7.mol

Synonyms:2H-3,9a-Methano-1-benzoxepin-9-methanol,octahydro-2,2,5a-trimethyl-, [3R-(3a,5aa,9a,9aa)]-; (-)-Baimuxinol; Baimuxinol

Chemical Property of baimuxinol

Chemical Property:

• Vapor Pressure: 0.000141mmHg at 25°C
• Boiling Point: 297°Cat760mmHg
• Flash Point: 106.7°C
• PSA: 29.46000
• Density: 1.05g/cm³
• LogP: 3.13280

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of baimuxinol

There total 4 articles about baimuxinol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

dehydrobaimuxinol (105013-74-9) → (-)-Baimuxinol (105013-72-7) + (-)-Isobaimuxinol (122798-42-9)

Guidance literature:

With hydrogen; Raney nickel W-2; In ethanol; for 3h; under 760 Torr; Ambient temperature;

DOI:10.1055/s-1992-26299

Reference yield:

5,11-oxy-5β,10α-eudesm-3-ene (5956-12-7) → (-)-Baimuxinol (105013-72-7)

Guidance literature:

Multi-step reaction with 2 steps

1: 35 percent / 5percent SeO₂/silica gel / dioxane / 1 h / Ambient temperature

2: 14 percent / H₂ / Raney nickel W-2 / ethanol / 3 h / 760 Torr / Ambient temperature

With selenium(IV) oxide; hydrogen; silica gel; Raney nickel W-2; In 1,4-dioxane; ethanol;

DOI:10.1055/s-1992-26299

Reference yield:

10-epieudesm-4-ene-3,11-diols (849949-32-2) → (-)-Baimuxinol (105013-72-7)

Guidance literature:

Multi-step reaction with 3 steps

1: 73 percent / conc. H₂SO₄ / benzene / 0.17 h / Ambient temperature

2: 35 percent / 5percent SeO₂/silica gel / dioxane / 1 h / Ambient temperature

3: 14 percent / H₂ / Raney nickel W-2 / ethanol / 3 h / 760 Torr / Ambient temperature

With selenium(IV) oxide; sulfuric acid; hydrogen; silica gel; Raney nickel W-2; In 1,4-dioxane; ethanol; benzene;

DOI:10.1055/s-1992-26299

upstream raw materials:

dehydrobaimuxinol

5,11-oxy-5β,10α-eudesm-3-ene

10-epieudesm-4-ene-3,11-diols

(+)-12-Oxo-α-agarofuran

Refernces