trans-1-Phenyl-1-pentene

Base Information

• Chemical Name: trans-1-Phenyl-1-pentene
• CAS No.: 16002-93-0
• Molecular Formula: C11H14
• Molecular Weight: 146.232
• European Community (EC) Number: 212-553-7,257-711-6
• Nikkaji Number: J124.859F,J799.075H
• Mol file: 16002-93-0.mol

Synonyms:trans-1-Phenyl-1-pentene;1-Pentenylbenzene;16002-93-0;Pentenylbenzene;826-18-6;[(E)-pent-1-enyl]benzene;Benzene, 1-pentenyl-;1-Pentene, 1-phenyl-;1-Phenylpentene;(E)-Pent-1-en-1-ylbenzene;(1E)-1-Pentenylbenzene;(e)-1-phenyl-1-pentene;Benzene, (1E)-1-penten-1-yl-;EINECS 212-553-7;EINECS 257-711-6;1-Phenyl-1-pentene;52181-77-8;(E)-pent-1-enylbenzene;(1E)-1-Penten-1-ylbenzene;KHMYONNPZWOTKW-UHFFFAOYSA-N;KHMYONNPZWOTKW-VMPITWQZSA-N;[(1E)-pent-1-en-1-yl]benzene;AKOS024262867;2H-Thiopyran-4-carboxylicacid,tetrahydro-(9CI);A928619

Chemical Property of trans-1-Phenyl-1-pentene

Chemical Property:

• Vapor Pressure: 0.218mmHg at 25°C
• Boiling Point: 215.3°Cat760mmHg
• Flash Point: 77.1°C
• PSA: 0.00000
• Density: 0.894g/cm³
• LogP: 3.49990
• XLogP3: 3.9
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 3
• Exact Mass: 146.109550447
• Heavy Atom Count: 11
• Complexity: 107

Purity/Quality:

98% ^*data from raw suppliers

trans-1-Phenyl-1-pentene 90% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCC=CC1=CC=CC=C1
• Isomeric SMILES: CCC/C=C/C1=CC=CC=C1

Technology Process of trans-1-Phenyl-1-pentene

There total 154 articles about trans-1-Phenyl-1-pentene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

1-Phenyl-1-pentanol (583-03-9) → pentylbenzene (538-68-1) + (E)-1-phenyl-1-pentene (16002-93-0)

Guidance literature:

With chloro-trimethyl-silane; benzoic acid; sodium iodide; In acetonitrile; at 75 ℃; for 20h; Yields of byproduct given;

DOI:10.1016/S0040-4039(01)80790-5

Reference yield: 75.0%

n-butyl(triphenyl)phosphonium bromide (1779-51-7) + benzaldehyde (100-52-7) → (Z)-pent-1-en-1-ylbenzene (7642-18-4) + (E)-1-phenyl-1-pentene (16002-93-0) + Triphenylphosphine oxide (791-28-6)

Guidance literature:

With potassium carbonate; In methanol; at 65 ℃; for 1h; Product distribution; Quantum yield; comparative studies with other arylaldehydes;

DOI:10.1016/S0040-4020(01)87536-0

Reference yield: 64.0%

C13H17N (370066-06-1) → pentylbenzene (538-68-1) + (E)-1-phenyl-1-pentene (16002-93-0)

Guidance literature:

With chloro(1,5-cyclooctadiene)rhodium(I) dimer; triisopropyl phosphite; chlorotriisopropylsilane; In ethyl-cyclohexane; at 160 ℃; for 15h; Inert atmosphere;

upstream raw materials:

1-iodo-butane

benzyl phenyl selenide

(benzylseleninyl)benzene

n-butyl magnesium bromide

Downstream raw materials:

5-phenylpentan-1-ol

(2R*,3R*)-2-phenyl-3-propyloxirane

(S,E)-1-phenylpent-1-en-3-amine

C₂₄H₃₀

Refernces

• 1、 Liu, Michael T. H.,Choe, Yoong-Kee,Kimura, Masahiro,Kobayashi, Kaoru,Nagase, Shigeru,Wakahara, Takatsugu,Niino, Yasuyuki,Ishitsuka, Midori O.,Maeda, Yutaka,Akasaka, Takeshi. "Effect of substituents on the thermal decomposition of diazirines: Experimental and computational studies". . p. 7471 - 7478. Retrieved 2003.
• 2、 Naitoh, Yoshitaka,Bando, Fumiaki,Terao, Jun,Otsuki, Kazutaka,Kuniyasu, Hitoshi,Kambe, Nobuaki. "Pd-catalyzed coupling reaction of allyl and propargyl ethers with chlorosilanes". . p. 236 - 237. Retrieved 2007.
• 3、 Fukuzawa, Shin-Ichi,Yamamoto, Masahisa,Kikuchi, Satoshi. "Unexpected 1,5-dilithiation of chiral o-TMS blocked (dimethylamino) phenylmethylferrocene: An alternative approach to chiral ferrocenyl 1,5-diphosphanes". . p. 1514 - 1517. Retrieved 2007.
• 4、 Zhang, Weijie,Qin, Ruixuan,Fu, Gang,Zheng, Nanfeng. "Heterogeneous Isomerization for Stereoselective Alkyne Hydrogenation to trans-Alkene Mediated by Frustrated Hydrogen Atoms". supporting information. p. 15882 - 15890. Retrieved 2021/10/02.
• 5、 Barham, Joshua P.,K?nig, Burkhard,Karl, Tobias A.,Reiter, Sebastian,Tian, Xianhai,Yakubov, Shahboz,de Vivie-Riedle, Regina. "Electro-mediated PhotoRedox Catalysis for Selective C(sp3)–O Cleavages of Phosphinated Alcohols to Carbanions". supporting information. p. 20817 - 20825. Retrieved 2021/08/18.