CID 14359

Base Information

• Chemical Name: CID 14359
• CAS No.: 1142-15-0
• Molecular Formula: C15H14O
• Molecular Weight: 228.337
• Hs Code.: 29093090
• DSSTox Substance ID: DTXSID80862562
• Mol file: 1142-15-0.mol

Synonyms:DTXSID80862562;AKOS030239288;FT-0633398

Chemical Property of CID 14359

Chemical Property:

• Appearance/Colour: WHITE TO VERY SLIGHTLY YELLOWISH CRYSTAL. POWDER
• Vapor Pressure: 0.000159mmHg at 25°C
• Melting Point: 135-138 °C
• Refractive Index: 1.634
• Boiling Point: 341.5 °C at 760 mmHg
• Flash Point: 135.4 °C
• PSA: 9.23000
• Density: 1.069 g/cm³
• LogP: 3.86560
• Storage Temp.: Sealed in dry,Room Temperature
• Water Solubility.: Sparingly soluble (0.061 g/L) (25°C) in water.
• XLogP3: 4.4
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 3
• Exact Mass: 210.104465066
• Heavy Atom Count: 16
• Complexity: 208

Purity/Quality:

97% ^*data from raw suppliers

4-Methoxystilbene ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36
• Safety Statements: 39-26

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: COC1=CC=C(C=C1)C=CC2=CC=CC=C2
• Uses: It is used in the modification of the photochemical behavior of organic molecules by cyclodextrin.

Technology Process of CID 14359

There total 4 articles about CID 14359 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 43.0%

4(C5H5)(1-)*2Zr(4+)*2(NNCHC6H4CH3)(2-)=((C5H5)2ZrNNCHC6H4CH3)2 (105336-82-1) + cyclohexanecarbaldehyde (2043-61-0) → 1-(2-cyclohexylvinyl)-4-methylbenzene (105371-94-6) + C6H11CHN2CHC6H4CH3 (1142-15-0)

Guidance literature:

In benzene-d6; N2 atm., C6D6, 10°C;; detected by NMR spectroscopy;; Kinetics;

DOI:10.1021/om00145a030

Reference yield:

E-1-(phenyl)-2-(4'-methoxyphenyl)ethene (1694-19-5) → 4-methoxy-trans-stilbene radical-cation (1142-15-0,1657-53-0,1694-19-5,130059-90-4,130059-94-8)

Guidance literature:

With 9,10-Dicyanoanthracene; In acetonitrile; Quantum yield; Thermodynamic data; Irradiation; Φ_sep, -ΔG_-et; other electron acceptors; quantum yield for separation of initially formed radical ion pair to generate free stilbene cation radical;

DOI:10.1021/ja00178a031

Reference yield:

1-Methoxy-4-((Z)-styryl)-benzene (1142-15-0,1657-53-0,1694-19-5,130059-90-4,130059-94-8) → 4-methoxy-trans-stilbene radical-cation (1142-15-0,1657-53-0,1694-19-5,130059-90-4,130059-94-8)

Guidance literature:

In 1,2-dichloro-ethane; Rate constant; Ambient temperature; Irradiation;

DOI:10.1021/jo00120a004 DOI:10.1021/jp9609904

upstream raw materials:

cis-4-methoxystilbene

E-1-(phenyl)-2-(4'-methoxyphenyl)ethene

1-Methoxy-4-((Z)-styryl)-benzene

4(C₅H₅)^(1-)*2Zr⁽⁴⁺⁾*2(NNCHC₆H₄CH₃)^(2-)=((C₅H₅)2ZrNNCHC₆H₄CH₃)2

Downstream raw materials:

4-methoxy-trans-stilbene radical-cation