α,α-Diphenylnaphthalene-1-methanol

Base Information

• Chemical Name: α,α-Diphenylnaphthalene-1-methanol
• CAS No.: 630-95-5
• Molecular Formula: C23H18O
• Molecular Weight: 310.395
• Mol file: 630-95-5.mol

Synonyms:naphthyldiphenylmethanol;1-Naphthalenemethanol, α,α-diphenyl-;Naphthalen-1-yl-diphenyl-methanol;

Chemical Property of α,α-Diphenylnaphthalene-1-methanol

Chemical Property:

• Vapor Pressure: 8.49E-11mmHg at 25°C
• Melting Point: 136.5°C
• Refractive Index: 1.6380 (estimate)
• Boiling Point: 499.5°C at 760 mmHg
• Flash Point: 197.5°C
• PSA: 20.23000
• Density: 1.173g/cm³
• LogP: 5.12400

Purity/Quality:

99% ^*data from raw suppliers

DIPHENYL-ALPHA-NAPHTHYLCARBINOL 98.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of α,α-Diphenylnaphthalene-1-methanol

There total 29 articles about α,α-Diphenylnaphthalene-1-methanol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

benzophenone (119-61-9) + 1-Bromonaphthalene (90-11-9) → 1-naphthyldiphenylmethanol (630-95-5)

Guidance literature:

1-Bromonaphthalene; With 3-(chloromethyl)heptane; sodium; In tetrahydrofuran; hexane; at -40 ℃; for 0.000361111h; Flow reactor;

benzophenone; In tetrahydrofuran; hexane; at -20 ℃; for 0.166667h; Temperature; Time; Flow reactor;

DOI:10.1002/anie.202103031

Reference yield: 87.0%

benzophenone (119-61-9) + 1-naphthylmagnesiumbromide (703-55-9) → 1-naphthyldiphenylmethanol (630-95-5)

Guidance literature:

DOI:10.1016/j.tetasy.2009.10.028

Reference yield: 50.0%

1-Iodonaphthalene (90-14-2) + tetraphenylethane-1,2-diol (464-72-2) → 1-naphthyldiphenylmethanol (630-95-5)

Guidance literature:

tetraphenylethane-1,2-diol; With sodium hydride; In tetrahydrofuran; at 20 ℃; for 0.0833333h; Inert atmosphere; Schlenk technique;

1-Iodonaphthalene; In tetrahydrofuran; at 20 ℃; for 20h; Inert atmosphere; Schlenk technique;

DOI:10.1021/acs.orglett.6b02184

upstream raw materials:

bromobenzene

1-benzoylnaphthalene

benzophenone

1-Bromonaphthalene

Downstream raw materials:

1-benzhydrylnaphthalene

1-(α-bromo-benzhydryl)-naphthalene

dicyclohexylmethane

11-phenylbenzofluorene