butyl(1-methylethoxy)magnesium

Base Information

• Chemical Name: butyl(1-methylethoxy)magnesium
• CAS No.: 10175-15-2
• Molecular Formula: C7H16 Mg O
• Molecular Weight: 140.508
• Mol file: 10175-15-2.mol

Synonyms:Magnesium,butylisopropoxy- (7CI,8CI); Butyl(1-methylethoxy)magnesium;Butylisopropoxymagnesium

Chemical Property of butyl(1-methylethoxy)magnesium

Chemical Property:

• Vapor Pressure: 1920mmHg at 25°C
• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 9.23000
• Density: g/cm³
• LogP: 2.62980

Purity/Quality:

98%,99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of butyl(1-methylethoxy)magnesium

There total 2 articles about butyl(1-methylethoxy)magnesium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

n-butyl magnesium bromide (693-03-8) + sodium isopropylate (683-60-3) → butyl(1-methylethoxy)magnesium (10175-15-2)

Guidance literature:

In tetrahydrofuran; at 0 - 5 ℃;

DOI:10.1016/0022-328X(93)83163-P

Reference yield:

→ butyl(1-methylethoxy)magnesium (10175-15-2)

Guidance literature:

BuCl, Mg, i-PrOH;

DOI:10.1039/c19660000559

Reference yield:

butyl(1-methylethoxy)magnesium (10175-15-2) + benzaldehyde (100-52-7) → (S)-(-)-1-phenylpentanol (33652-83-4) + (R)-1-phenylpentan-1-ol (19641-53-3)

Guidance literature:

titanium(IV) isopropylate; chiral sulfonamide; In toluene; at 0 ℃; for 4h; Yield given. Yields of byproduct given;

DOI:10.1016/S0040-4039(00)99546-7

upstream raw materials:

n-butyl magnesium bromide

sodium isopropylate

Downstream raw materials:

(S)-(-)-1-phenylpentanol

(R)-1-phenylpentan-1-ol

Refernces

• 1、 Gupta, Shamma,Sharma, Sangeeta,Narula, A. K.. "Synthesis of organomagnesium β-diketonates and alkoxides". . p. 1 - 4. Retrieved 2007/10/02.