Decyl(trimethyl)silane

Base Information

• Chemical Name: Decyl(trimethyl)silane
• CAS No.: 18414-75-0
• Molecular Formula: C13H30Si
• Molecular Weight: 214.467
• NSC Number: 106791
• DSSTox Substance ID: DTXSID80296005
• Nikkaji Number: J404.101A
• Wikidata: Q82036295
• Mol file: 18414-75-0.mol

Synonyms:18414-75-0;decyl(trimethyl)silane;decyltrimethylsilane;5112-85-6;decyl-trimethyl-silane;NSC106791;DTXSID80296005;NSC-106791

Chemical Property of Decyl(trimethyl)silane

Chemical Property:

• Vapor Pressure: 0.0468mmHg at 25°C
• Boiling Point: 244.7°C at 760 mmHg
• Flash Point: 87.3°C
• PSA: 0.00000
• Density: 0.769g/cm³
• LogP: 5.46530
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 9
• Exact Mass: 214.211677491
• Heavy Atom Count: 14
• Complexity: 113

Purity/Quality:

98%min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCCCCCCCC[Si](C)(C)C

Technology Process of Decyl(trimethyl)silane

There total 5 articles about Decyl(trimethyl)silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

n-decyltrichlorosilane (13829-21-5) → n-decyltrimethylsilane (18414-75-0)

Guidance literature:

With CH₃MgBr; In not given;

DOI:10.1021/ja01207a035

Reference yield:

chloro-trimethyl-silane (75-77-4) + (n-decylthio)benzene (13910-18-4) → n-decyltrimethylsilane (18414-75-0)

Guidance literature:

With sodium; In tetrahydrofuran;

DOI:10.1246/cl.1978.383

Reference yield:

Deca-1,2-dienyl-trimethyl-silane (74052-12-3) → n-decyltrimethylsilane (18414-75-0) + (E)-1-(trimethylsilyl)-1-decene (71779-75-4)

Guidance literature:

With water; diisobutylaluminium hydride; Multistep reaction; 1.) hexane, 15 h, 60°C; 2.) 0°C;

DOI:10.1016/S0040-4039(00)93622-0

upstream raw materials:

chloro-trimethyl-silane

(n-decylthio)benzene

n-decyl magnesium bromide

Deca-1,2-dienyl-trimethyl-silane

Downstream raw materials:

1-Decanol