biphenyl-2-yl benzoate

Base Information

• Chemical Name: biphenyl-2-yl benzoate
• CAS No.: 5449-49-0
• Molecular Formula: C19H14O2
• Molecular Weight: 274.319
• Mol file: 5449-49-0.mol

Synonyms:

Chemical Property of biphenyl-2-yl benzoate

Chemical Property:

• Vapor Pressure: 4.48E-09mmHg at 25°C
• Boiling Point: 471.9°C at 760 mmHg
• Flash Point: 199.8°C
• Density: 1.151g/cm³

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of biphenyl-2-yl benzoate

There total 15 articles about biphenyl-2-yl benzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.8%

benzoyl chloride (98-88-4) + 2-Phenylphenol (90-43-7,287950-96-3) → [1,1'-biphenyl]-2-yl benzoate (5449-49-0)

Guidance literature:

With triethylamine; In toluene; at 30 ℃; for 2.75h; Cooling with ice;

Reference yield: 85.0%

iodobenzene (591-50-4) + 3-oxobenzo[d]isothiazole-2(3H)-carbaldehyde 1,1-dioxide (50978-45-5) + 2-Phenylphenol (90-43-7,287950-96-3) → [1,1'-biphenyl]-2-yl benzoate (5449-49-0)

Guidance literature:

With palladium 10% on activated carbon; sodium carbonate; at 80 ℃; for 18h; Green chemistry;

DOI:10.1039/c6gc03027k

Reference yield: 83.0%

2-iodobiphenyl (2113-51-1) + benzoic acid (65-85-0,8013-63-6) → [1,1'-biphenyl]-2-yl benzoate (5449-49-0)

Guidance literature:

With palladium(II) trifluoroacetate; 4,7-dimethoxy-1,10-phenanthroline; silver trifluoroacetate; at 150 ℃; for 15h; chemoselective reaction; Schlenk technique; Sealed tube;

DOI:10.1002/adsc.201901136

upstream raw materials:

benzyl chloride

2-Phenylphenol

benzoic acid

2-iodophenyl benzoate

Refernces

• 1、 -. "Method for preparing carboxylate aryl type compound". Paragraph 0135-0140. . Retrieved 2020/02/10.
• 2、 Gaikwad, Vinayak V.,Bhanage, Bhalchandra M.. "Oxime palladacycle in PEG as a highly efficient and recyclable catalytic system for phenoxycarbonylation of aryl iodides with phenols". . . Retrieved 2019/02/19.