Ethanone, 1-(4,5-dihydro-2-methyl-5,5-diphenyl-3-furanyl)-

Base Information

• Chemical Name: Ethanone, 1-(4,5-dihydro-2-methyl-5,5-diphenyl-3-furanyl)-
• CAS No.: 102860-77-5
• Molecular Formula: C19H18O2
• Molecular Weight: 278.351
• DSSTox Substance ID: DTXSID60464846
• Nikkaji Number: J387.727B
• Wikidata: Q82290363
• Mol file: 102860-77-5.mol

Synonyms:102860-77-5;Ethanone, 1-(4,5-dihydro-2-methyl-5,5-diphenyl-3-furanyl)-;DTXSID60464846;3-acetyl-2-methyl-5,5-diphenyl-4,5-dihydrofuran;1-(2-Methyl-5,5-diphenyl-4,5-dihydrofuran-3-yl)ethanone;1-(2-Methyl-5,5-diphenyl-4,5-dihydro-furan-3-yl)-ethanone

Chemical Property of Ethanone, 1-(4,5-dihydro-2-methyl-5,5-diphenyl-3-furanyl)-

Chemical Property:

• XLogP3: 3.6
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 3
• Exact Mass: 278.130679813
• Heavy Atom Count: 21
• Complexity: 405

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC1=C(CC(O1)(C2=CC=CC=C2)C3=CC=CC=C3)C(=O)C

Technology Process of Ethanone, 1-(4,5-dihydro-2-methyl-5,5-diphenyl-3-furanyl)-

There total 11 articles about Ethanone, 1-(4,5-dihydro-2-methyl-5,5-diphenyl-3-furanyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

1,1-Diphenylethylene (530-48-3) + acetylacetone (123-54-6,81235-32-7) → 1-(2-methyl-5,5-diphenyl-4,5-dihydrofuran-3-yl)ethan-1-one (102860-77-5)

Guidance literature:

With formic acid; manganese(III) triacetate dihydrate; acetic acid; at 100 ℃; for 0.00833333h; Inert atmosphere;

DOI:10.1080/00397911.2015.1049618

Reference yield: 89.0%

1,1-Diphenylethylene (530-48-3) → benzophenone (119-61-9) + 1-(2-methyl-5,5-diphenyl-4,5-dihydrofuran-3-yl)ethan-1-one (102860-77-5)

Guidance literature:

With manganese(III) acetylacetonate; In acetic acid; for 0.0416667h; Heating;

DOI:10.1246/bcsj.58.1922

Reference yield: 89.0%

1,1-Diphenylethylene (530-48-3) + tris(2,4-pentanedionato)manganese(III) → benzophenone (119-61-9) + 1-(2-methyl-5,5-diphenyl-4,5-dihydrofuran-3-yl)ethan-1-one (102860-77-5)

Guidance literature:

In acetic acid; for 0.0416667h; Product distribution; Heating; various solvents, time, additives, other Mn complex;

DOI:10.1246/bcsj.58.1922

upstream raw materials:

1,1-Diphenylethylene

manganese(III) acetylacetonate

acetylacetone

3,5-diacetylheptane-2,6-dione

Downstream raw materials:

1-methyl-4-phenylnaphthalene

5,5-diphenyl-4-penten-2-one