Borane, (1-cyclohexen-1-ylmethyl)dipropyl-

Base Information

• Chemical Name: Borane, (1-cyclohexen-1-ylmethyl)dipropyl-
• CAS No.: 103496-31-7
• Molecular Formula: C13H25B
• Molecular Weight: 192.153
• Mol file: 103496-31-7.mol

Synonyms:

Chemical Property of Borane, (1-cyclohexen-1-ylmethyl)dipropyl-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Borane, (1-cyclohexen-1-ylmethyl)dipropyl-

There total 2 articles about Borane, (1-cyclohexen-1-ylmethyl)dipropyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

methoxy(dipropyl)borane (2938-89-8) + 1-bromomethylcyclohexene (37677-17-1) → 1-(dipropylborylmethyl)cyclohexene (103496-31-7)

Guidance literature:

With aluminium; In not given; according to Yu. N. Bubnov, L. I. Lavrinovich, Tetrahedron Lett., 26, 4551 (1986);

DOI:10.1351/pac198759070895

Reference yield: 61.0%

methoxy(dipropyl)borane (2938-89-8) + 1-bromomethylcyclohexene (37677-17-1) + aluminium (7429-90-5) → 1-(dipropylborylmethyl)cyclohexene (103496-31-7)

Guidance literature:

With mercury dichloride; In diethyl ether; Ar atmosphere; addn. of Al, mercuric chloride and ether to cyclohexene- and B-derivatives (over 1 h, stirring, refluxing), refluxing (12 h); distn., redistn. (vac.); elem. anal.;

DOI:10.1007/BF00957440

Reference yield: 65.7%

1-(dipropylborylmethyl)cyclohexene (103496-31-7) + benzonitrile (100-47-0) → {(2-methylenecyclohexen-1-yl)phenylketimino}di(n-propyl)borane (152168-09-7)

Guidance literature:

In pentane; Ar;; solvent removed; distd. (140-143°C, 1 mmHg); elem. anal.;;

DOI:10.1007/BF00863372

upstream raw materials:

methoxy(dipropyl)borane

1-bromomethylcyclohexene

aluminium

Downstream raw materials:

2-(hydroxymethyl)-1-methylenecyclohexane

4-(2-Methylene-cyclohexyl)-heptane-4-thiol

methylenecyclohexane

1-(2-Methylene-cyclohexyl)-ethanol