Stannane, (cyclopropylmethyl)trimethyl-

Base Information

• Chemical Name: Stannane, (cyclopropylmethyl)trimethyl-
• CAS No.: 51675-53-7
• Molecular Formula: C7H16Sn
• Molecular Weight: 218.914
• DSSTox Substance ID: DTXSID00199620
• Mol file: 51675-53-7.mol

Synonyms:Stannane, (cyclopropylmethyl)trimethyl-;51675-53-7;Stannane,(cyclopropylmethyl)trimethyl-;DTXSID00199620

Chemical Property of Stannane, (cyclopropylmethyl)trimethyl-

Chemical Property:

• Vapor Pressure: 2.66mmHg at 25°C
• Boiling Point: 163.8°C at 760 mmHg
• Flash Point: 47.1°C
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 2
• Exact Mass: 220.027403
• Heavy Atom Count: 8
• Complexity: 76.9

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C[Sn](C)(C)CC1CC1

Technology Process of Stannane, (cyclopropylmethyl)trimethyl-

There total 3 articles about Stannane, (cyclopropylmethyl)trimethyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

cyclopropylmethyl iodide (33574-02-6) + potassium trimethylstannate (38423-82-4) → methylcyclopropane (594-11-6) + (3-butenyl)trimethylstannane (17314-38-4) + (Cyclopropylcarbinyl)trimethylstannane (51675-53-7)

Guidance literature:

With tert-butylamine; In tetrahydrofuran; at 0 ℃; Product distribution; Mechanism; other addend;

DOI:10.1021/jo00181a027

Reference yield:

cyclopropylmethyl iodide (33574-02-6) + trimethylstannyl sodium (16643-09-7) → 1-butylene (106-98-9,9003-28-5) + methylcyclopropane (594-11-6) + (3-butenyl)trimethylstannane (17314-38-4) + (Cyclopropylcarbinyl)trimethylstannane (51675-53-7)

Guidance literature:

With tert-butylamine; In tetrahydrofuran; at 0 ℃; Product distribution; Mechanism; other addend;

DOI:10.1021/jo00181a027

Reference yield:

cyclopropylmethyl iodide (33574-02-6) + lithium trimethylstannyl (17946-71-3) → 1-butylene (106-98-9,9003-28-5) + methylcyclopropane (594-11-6) + (3-butenyl)trimethylstannane (17314-38-4) + (Cyclopropylcarbinyl)trimethylstannane (51675-53-7)

Guidance literature:

With tert-butylamine; In tetrahydrofuran; at 0 ℃; Product distribution; Mechanism; other addend;

DOI:10.1021/jo00181a027

upstream raw materials:

cyclopropylmethyl iodide

potassium trimethylstannate

trimethylstannyl sodium

lithium trimethylstannyl

Downstream raw materials:

1-butylene

4-iodobut-1-ene

Refernces