Benzene, 1-methyl-4-[(1-methylenebutyl)sulfonyl]-

Base Information

Chemical Name:Benzene, 1-methyl-4-[(1-methylenebutyl)sulfonyl]-
CAS No.:105235-53-8
Molecular Formula:C12H16O2S
Molecular Weight:224.324
Hs Code.:
DSSTox Substance ID:DTXSID10474314
Wikidata:Q82304244
Mol file:105235-53-8.mol

Synonyms:105235-53-8;Benzene, 1-methyl-4-[(1-methylenebutyl)sulfonyl]-;DTXSID10474314

Suppliers and Price of Benzene, 1-methyl-4-[(1-methylenebutyl)sulfonyl]-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Benzene, 1-methyl-4-[(1-methylenebutyl)sulfonyl]-

Chemical Property:

XLogP3:3.2
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:4
Exact Mass:224.08710092
Heavy Atom Count:15
Complexity:303

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CCCC(=C)S(=O)(=O)C1=CC=C(C=C1)C

Technology Process of Benzene, 1-methyl-4-[(1-methylenebutyl)sulfonyl]-

There total 7 articles about Benzene, 1-methyl-4-[(1-methylenebutyl)sulfonyl]- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 105465-45-0
1-[2-(Toluene-4-sulfonyl)-pentyl]-pyrrolidine

: 105235-53-8
2-tosyl-1-pentene

Guidance literature:: With sodium hydrogencarbonate; 3-chloro-benzenecarboperoxoic acid; In dichloromethane; for 48h; Ambient temperature;
DOI:10.1246/cl.1986.341

Reference yield: 60.0%

: 906537-76-6
1-((3-bromoprop-1-en-2-yl)sulfonyl)-4-methylbenzene

: 930-68-7
cyclohexenone

: 557-20-0
diethylzinc

: 3-ethyl-2-[2-(p-tolylsulfonyl)allyl]cyclohexanone

: 3-ethyl-2-[2-(p-tolylsulfonyl)allyl]cyclohexanone

: 105235-53-8
2-tosyl-1-pentene

Guidance literature:: cyclohexenone; diethylzinc; With copper(I) thiophene-2-carboxylate; chiral 2,2'-biphenyl-derived (R,R)-phosphine ligand; In diethyl ether; hexane; at -30 ℃; for 0.333333h;

1-(3-bromo-prop-1-ene-2-sulfonyl)-4-methyl-benzene; In diethyl ether; hexane; at 20 ℃; for 7h;
DOI:10.1021/jo060814j

Reference yield:

: 16191-66-5
1-[2-(toluene-4-sulfonyl)-ethyl]-pyrrolidine

: 105235-53-8
2-tosyl-1-pentene

Guidance literature:: Multi-step reaction with 2 steps

1: 1.) butyllithium (BuLi), HMPA / 1.)THF, hexane, -72 deg C, 30 min; 2.) THF, -72 deg C, 1 h

2: 90 percent / m-chloroperbenzoic acid (MCPBA), sodium hydrocarbonate (NaHCO₃) / CH₂Cl₂ / 48 h / Ambient temperature

With N,N,N,N,N,N-hexamethylphosphoric triamide; n-butyllithium; sodium hydrogencarbonate; 3-chloro-benzenecarboperoxoic acid; In dichloromethane;
DOI:10.1246/cl.1986.341