Boranamine, N,1,1-tris(2,4,6-trimethylphenyl)-

Base Information

• Chemical Name: Boranamine, N,1,1-tris(2,4,6-trimethylphenyl)-
• CAS No.: 109151-64-6
• Molecular Formula: C27H34BN
• Molecular Weight: 383.37700
• Mol file: 109151-64-6.mol

Synonyms:Boranamine,N,1,1-tris(2,4,6-trimethylphenyl);

Chemical Property of Boranamine, N,1,1-tris(2,4,6-trimethylphenyl)-

Chemical Property:

• Boiling Point: 498.4±55.0 °C(Predicted)
• PSA: 12.03000
• Density: 1.00±0.1 g/cm3(Predicted)
• LogP: 5.75300

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Boranamine, N,1,1-tris(2,4,6-trimethylphenyl)-

There total 1 articles about Boranamine, N,1,1-tris(2,4,6-trimethylphenyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

dimesitylfluoroborane (436-59-9) → HNMesBMes2 (109151-64-6)

Guidance literature:

With LiN(H)C₆H₂(CH₃)3; In diethyl ether; protective gas: nitrogen; dropwise addn. of dimesitylboronfluoride in etheric soln. to stirred (1 h) soln. of LiN(H)HC6H2(CH3)3 (in situ from mesidine and n-BuLi in Et2O/0°C); stirring of yellow soln. (12 h);; evapn.; residue dissolved in toluene; filtration; concn. (vac.); cooling (-20°C/12 h);;

DOI:10.1021/ja00250a016

Reference yield: 80.0%

HNMesBMes2 (109151-64-6) + diethyl ether (60-29-7,927820-24-4) → Li(Et2O)2NMesBMes2 (124855-16-9)

Guidance literature:

With n-C₄H₉Li; In diethyl ether; hexane; addn. of BuLi in hexane to HNMesBMes2 in Et2O cooled in ice bath, stirring 30 min. (N2); filtration, evapn., cooling to -20°C for 12 h, crystn.;

Reference yield: 70.0%

HNMesBMes2 (109151-64-6) + NiBr2*5/3(THF) → {Ni(N(2,4,6-trimethylphenyl)B(2,4,6-trimethylphenyl)2)2} (119011-38-0)

Guidance literature:

With n-C₄H₉Li; In diethyl ether; hexane; dropwise addn. of BuLi in hexane to HNMesBMes2 in Et2O at 0°C, stirring 30 min., dropwise addn. to NiCl2.5/3(THF)2 in Et2O, stirring 2 h at room temp. (N2); evapn., extn. (hexane), filtration, evapn., cooling to -20°C overnight, crystn.;

upstream raw materials:

dimesitylfluoroborane

Downstream raw materials:

{Ni(N(2,4,6-trimethylphenyl)B(2,4,6-trimethylphenyl)2)2}

Li(Et₂O)2NMesBMes₂