Technology Process of 4-Pentenoic acid, 2-(phenylmethoxy)-, methyl ester, (S)-
There total 5 articles about 4-Pentenoic acid, 2-(phenylmethoxy)-, methyl ester, (S)- which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
(2S)-N-(2-benzyloxy-4-pentenoyl)-morpholine;
With
iodine;
In
1,2-dimethoxyethane; water;
at 23 ℃;
for 0.166667h;
With
acetic acid; zinc;
at 65 ℃;
for 1.5h;
methanol;
With
diazomethyl-trimethyl-silane;
Further stages.;
DOI:10.1021/ja015612d
- Guidance literature:
-
With
diammonium phosphate; manganese(II) sulfate; yeast ext; magnesium sulfate; iron(II) sulfate; zinc(II) sulfate;
In
water;
at 30 ℃;
for 24h;
suspension of grown cells of Corynebacterium equi IFO 3730, pH = 7.2, e.e. > 99percent;
DOI:10.1016/S0040-4039(00)95353-X
- Guidance literature:
-
Multi-step reaction with 2 steps
1.1: {Mg{1,2-bis[(oxazolin-2-yl)-4-(R)-(p-MeOPh)]-4,5-Cl2}C6H2}I2; i-Pr2NEt / CH2Cl2 / 12 h / -20 °C
2.1: I2 / H2O; 1,2-dimethoxy-ethane / 0.17 h / 23 °C
2.2: AcOH; Zn / 1.5 h / 65 °C
2.3: 52 percent / TMS-CHN2 / various solvent(s)
With
{Mg{1,2-bis[(oxazolin-2-yl)-4-(R)-(p-MeOPh)]-4,5-Cl2}C6H2}I2; iodine; N-ethyl-N,N-diisopropylamine;
In
1,2-dimethoxyethane; dichloromethane; water;
1.1: Acyl-Claisen rearrangement;
DOI:10.1021/ja015612d
