Benzaldehyde, 3-[2-[2-[4-[[6-(bromomethyl)-2,2-dimethyl-1,3-benzodioxol-4-yl]oxy]phen yl]ethyl]-6-(phenylmethoxy)phenoxy]-

Base Information

Chemical Name:Benzaldehyde, 3-[2-[2-[4-[[6-(bromomethyl)-2,2-dimethyl-1,3-benzodioxol-4-yl]oxy]phen yl]ethyl]-6-(phenylmethoxy)phenoxy]-
CAS No.:111436-57-8
Molecular Formula:C38H33BrO6
Molecular Weight:665.58
Hs Code.:
Mol file:111436-57-8.mol

Synonyms:

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Chemical Property of Benzaldehyde, 3-[2-[2-[4-[[6-(bromomethyl)-2,2-dimethyl-1,3-benzodioxol-4-yl]oxy]phen yl]ethyl]-6-(phenylmethoxy)phenoxy]-

Chemical Property:

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Technology Process of Benzaldehyde, 3-[2-[2-[4-[[6-(bromomethyl)-2,2-dimethyl-1,3-benzodioxol-4-yl]oxy]phen yl]ethyl]-6-(phenylmethoxy)phenoxy]-

There total 12 articles about Benzaldehyde, 3-[2-[2-[4-[[6-(bromomethyl)-2,2-dimethyl-1,3-benzodioxol-4-yl]oxy]phen yl]ethyl]-6-(phenylmethoxy)phenoxy]- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 96643-04-8
3-(2-Benzyloxy-6-{2-[4-(6-hydroxymethyl-2,2-dimethyl-benzo[1,3]dioxol-4-yloxy)-phenyl]-ethyl}-phenoxy)-benzaldehyde

: 111436-57-8
3-(2-Benzyloxy-6-{2-[4-(6-bromomethyl-2,2-dimethyl-benzo[1,3]dioxol-4-yloxy)-phenyl]-ethyl}-phenoxy)-benzaldehyde

Guidance literature:: With dibromo sulfoxide;
DOI:10.1016/S0040-4039(00)61953-6

Reference yield:

: 81464-85-9
2,3-Bis(benzyloxy)benzyl bromide

: 111436-57-8
3-(2-Benzyloxy-6-{2-[4-(6-bromomethyl-2,2-dimethyl-benzo[1,3]dioxol-4-yloxy)-phenyl]-ethyl}-phenoxy)-benzaldehyde

Guidance literature:: Multi-step reaction with 7 steps

1: 74 percent / 3 h / 80 °C

2: 1.) potassium tert-butoxide / 1.) DMF, 0 deg C, 15 min, 2.) DMF, RT, 12 h

3: 96 percent / H₂ / 10percent Pd/C / methanol; ethyl acetate / 760 Torr / Ambient temperature

4: 67 percent / K₂CO₃ / acetone / Heating

5: 94 percent / LiAlH₄ / tetrahydrofuran / Ambient temperature

6: 42 percent / K₂CO₃, CuO, pyridine, quinoline / 6 h / 170 °C

7: SOBr₂ / benzene / 1 h / 0 °C

With pyridine; quinoline; lithium aluminium tetrahydride; dibromo sulfoxide; potassium tert-butylate; hydrogen; potassium carbonate; copper(II) oxide; palladium on activated charcoal; In tetrahydrofuran; methanol; ethyl acetate; acetone; benzene;
DOI:10.1021/jo00236a015

Reference yield:

: 96642-99-8
diethyl <<2,3-bis(benzyloxy)phenyl>methyl>phosphonate

: 111436-57-8
3-(2-Benzyloxy-6-{2-[4-(6-bromomethyl-2,2-dimethyl-benzo[1,3]dioxol-4-yloxy)-phenyl]-ethyl}-phenoxy)-benzaldehyde

Guidance literature:: Multi-step reaction with 6 steps

1: 1.) potassium tert-butoxide / 1.) DMF, 0 deg C, 15 min, 2.) DMF, RT, 12 h

2: 96 percent / H₂ / 10percent Pd/C / methanol; ethyl acetate / 760 Torr / Ambient temperature

3: 67 percent / K₂CO₃ / acetone / Heating

4: 94 percent / LiAlH₄ / tetrahydrofuran / Ambient temperature

5: 42 percent / K₂CO₃, CuO, pyridine, quinoline / 6 h / 170 °C

6: SOBr₂ / benzene / 1 h / 0 °C

With pyridine; quinoline; lithium aluminium tetrahydride; dibromo sulfoxide; potassium tert-butylate; hydrogen; potassium carbonate; copper(II) oxide; palladium on activated charcoal; In tetrahydrofuran; methanol; ethyl acetate; acetone; benzene;
DOI:10.1021/jo00236a015