1,1'-{[3-(Bromomethyl)-1,2-phenylene]bis(oxymethylene)}dibenzene

Base Information

Chemical Name:1,1'-{[3-(Bromomethyl)-1,2-phenylene]bis(oxymethylene)}dibenzene
CAS No.:81464-85-9
Molecular Formula:C21H19BrO2
Molecular Weight:383.285
Hs Code.:
DSSTox Substance ID:DTXSID60554357
Nikkaji Number:J893.398G
Wikidata:Q82435317

Synonyms:81464-85-9;DTXSID60554357;1,1'-{[3-(Bromomethyl)-1,2-phenylene]bis(oxymethylene)}dibenzene

Suppliers and Price of 1,1'-{[3-(Bromomethyl)-1,2-phenylene]bis(oxymethylene)}dibenzene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 2 raw suppliers

Chemical Property of 1,1'-{[3-(Bromomethyl)-1,2-phenylene]bis(oxymethylene)}dibenzene

Chemical Property:

XLogP3:5.4
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:7
Exact Mass:382.05684
Heavy Atom Count:24
Complexity:337

Purity/Quality:: 85.0-99.8% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:C1=CC=C(C=C1)COC2=CC=CC(=C2OCC3=CC=CC=C3)CBr

Technology Process of 1,1'-{[3-(Bromomethyl)-1,2-phenylene]bis(oxymethylene)}dibenzene

There total 7 articles about 1,1'-{[3-(Bromomethyl)-1,2-phenylene]bis(oxymethylene)}dibenzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

: 81464-84-8
2,3-bis-benzyloxy-benzyl alcohol

: 81464-85-9
2,3-Bis(benzyloxy)benzyl bromide

Guidance literature:: With phosphorus tribromide; In tetrahydrofuran;
DOI:10.1016/0040-4039(94)80116-9 DOI:10.1016/S0040-4039(97)10026-0

Reference yield:

: 5779-91-9
2,3-bis(benzyloxy)benzaldehyde

: 81464-85-9
2,3-Bis(benzyloxy)benzyl bromide

Guidance literature:: Multi-step reaction with 2 steps

1: 80 percent / LiAlH₄ / tetrahydrofuran

2: 98 percent / PBr₃ / tetrahydrofuran

With lithium aluminium tetrahydride; phosphorus tribromide; In tetrahydrofuran;
DOI:10.1016/0040-4039(94)80116-9 DOI:10.1016/S0040-4039(97)10026-0

Reference yield:

: 24677-78-9
2,3-dihydroxybenzaldehyde

: 81464-85-9
2,3-Bis(benzyloxy)benzyl bromide

Guidance literature:: Multi-step reaction with 3 steps

1: K₂CO₃ / ethanol

2: 80 percent / LiAlH₄ / tetrahydrofuran

3: 98 percent / PBr₃ / tetrahydrofuran

With lithium aluminium tetrahydride; phosphorus tribromide; potassium carbonate; In tetrahydrofuran; ethanol;
DOI:10.1016/0040-4039(94)80116-9