3-Methyl-5-oxylato-1,2,3-oxadiazole-3-ium

Base Information

• Chemical Name: 3-Methyl-5-oxylato-1,2,3-oxadiazole-3-ium
• CAS No.: 6939-12-4
• Molecular Formula: C3H5N2O2+
• Molecular Weight: 100.077
• Hs Code.: 2914190090
• Mol file: 6939-12-4.mol

Synonyms:3-Methylsydnone;3-methyl-1,2,3-oxadiazol-3-ium-5-olate;KUYNWZKDWRYCIH-UHFFFAOYSA;N-methylsydnone;N-methylsidnone;Sydnone,3-methyl;3-Methyl-sydnon;

Chemical Property of 3-Methyl-5-oxylato-1,2,3-oxadiazole-3-ium

Chemical Property:

• PSA: 52.97000
• LogP: -0.35710

Purity/Quality:

85.0-99.8% ^*data from raw suppliers

3-Methylsydnone 95% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 3-Methyl-5-oxylato-1,2,3-oxadiazole-3-ium

There total 5 articles about 3-Methyl-5-oxylato-1,2,3-oxadiazole-3-ium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

N-nitrososarcosine (13256-22-9,55332-66-6,55332-68-8) → N-methylsydnone (6939-12-4)

Guidance literature:

With acetic anhydride; for 0.25h; Heating;

DOI:10.1021/j100386a022

Reference yield: 58.0%

3-methyl-N-nitroso-5-sydnone imine (17590-38-4) → N-methylsydnone (6939-12-4)

Guidance literature:

In acetone; for 6h; Heating;

DOI:10.1002/ardp.19933261005

Reference yield: 31.0%

sarcosine (107-97-1,25951-24-0) → N-methylsydnone (6939-12-4)

Guidance literature:

sarcosine; With hydrogenchloride; sodium nitrite; In water; at 0 - 20 ℃;

In acetic anhydride; for 0.0833333h; Reflux;

DOI:10.1039/d1cc02841c

upstream raw materials:

N-nitrososarcosine

acetic anhydride

3-methyl-N-nitroso-5-sydnone imine

sarcosine

Downstream raw materials:

4-(hydroxy-diphenyl-methyl)-3-methyl-sydnone

2-Methyl-6-(N-methylanilino)-4,7(2H)-indazolchinon

6-Anilino-2-methyl-4,7(2H)-indazolchinon

3-tert-Butyl-1-methyl-1H-1,2,4-diazaphosphol