[(1E)-penta-1,4-dienyl]cyclohexane

Base Information

Chemical Name:[(1E)-penta-1,4-dienyl]cyclohexane
CAS No.:67857-89-0
Molecular Formula:C11H18
Molecular Weight:150.2606
Hs Code.:
NSC Number:244875
DSSTox Substance ID:DTXSID00418383
Wikidata:Q82228898

Synonyms:NSC244875;67857-89-0;DTXSID00418383;NSC-244875

Suppliers and Price of [(1E)-penta-1,4-dienyl]cyclohexane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 3 raw suppliers

Chemical Property of [(1E)-penta-1,4-dienyl]cyclohexane

Chemical Property:

Vapor Pressure:0.492mmHg at 25°C
Boiling Point:199°Cat760mmHg
Flash Point:60.4°C
Density:0.881g/cm³
XLogP3:4.5
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:3
Exact Mass:150.140850574
Heavy Atom Count:11
Complexity:127

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C=CCC=CC1CCCCC1
Isomeric SMILES:C=CC/C=C/C1CCCCC1

Technology Process of [(1E)-penta-1,4-dienyl]cyclohexane

There total 5 articles about [(1E)-penta-1,4-dienyl]cyclohexane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

: 3066-75-9
allyl diethyl phosphate

: 931-48-6
2-cyclohexylacetylene

: 67857-89-0
(E)-penta-1,4-dienylcyclohexane

Guidance literature:: 2-cyclohexylacetylene; With [1,3-bis(2,6-di-iso-propylphenyl)imidazol-2-ylidene]copper(I) tert-butoxide; lithium tert-butoxide; In toluene; at 25 ℃; Inert atmosphere;

allyl diethyl phosphate; In toluene; at 45 ℃; for 20h; diastereoselective reaction; Inert atmosphere;
DOI:10.1021/jacs.7b02104

Reference yield:

: ((Z)-1-Ethylselanyl-penta-1,4-dienyl)-cyclohexane

: 67857-89-0
(E)-penta-1,4-dienylcyclohexane

Guidance literature:: With lithium aluminium tetrahydride; In tetrahydrofuran; Heating;
DOI:10.1055/s-1997-959

Reference yield:

: 195524-17-5
((Z)-1,2-Bis-ethylselanyl-vinyl)-cyclohexane

: 67857-89-0
(E)-penta-1,4-dienylcyclohexane

Guidance literature:: Multi-step reaction with 2 steps

1: NiCl₂(PPh₃)2 / tetrahydrofuran / -50 °C

2: LiAlH₄ / tetrahydrofuran / Heating

With bis(triphenylphosphine)nickel(II) chloride; lithium aluminium tetrahydride; In tetrahydrofuran;
DOI:10.1055/s-1997-959