3,3'-Dichlorodibenzoyl peroxide

Base Information

• Chemical Name: 3,3'-Dichlorodibenzoyl peroxide
• CAS No.: 845-30-7
• Molecular Formula: C14H8 Cl2 O4
• Molecular Weight: 311.121
• Hs Code.: 2916399090
• European Community (EC) Number: 617-581-7
• UNII: 388KU8W0WX
• DSSTox Substance ID: DTXSID40233491
• Nikkaji Number: J378.638B
• Wikidata: Q27256765
• Mol file: 845-30-7.mol

Synonyms:3,3'-dichlorodibenzoyl peroxide;3,3-DDBP

Chemical Property of 3,3'-Dichlorodibenzoyl peroxide

Chemical Property:

• Vapor Pressure: 1.32E-07mmHg at 25°C
• Boiling Point: 430.2°C at 760 mmHg
• Flash Point: 175.5°C
• PSA: 52.60000
• Density: 1.433g/cm³
• LogP: 3.92220
• XLogP3: 4.8
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 5
• Exact Mass: 309.9799641
• Heavy Atom Count: 20
• Complexity: 327

Purity/Quality:

99.90% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC(=CC(=C1)Cl)C(=O)OOC(=O)C2=CC(=CC=C2)Cl

Technology Process of 3,3'-Dichlorodibenzoyl peroxide

There total 6 articles about 3,3'-Dichlorodibenzoyl peroxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

m-Chlorobenzoyl chloride (618-46-2) → m-chlorobenzoyl peroxide (845-30-7)

Guidance literature:

With dihydrogen peroxide; In diethyl ether; water; for 0.166667h;

DOI:10.1021/ol900756g

Reference yield: 69.0%

3-chloro-benzenecarboperoxoic acid (937-14-4) → m-chlorobenzoyl peroxide (845-30-7)

Guidance literature:

With dicyclohexyl-carbodiimide; In dichloromethane; at 20 ℃; for 1.75h;

DOI:10.1248/cpb.54.1412

Reference yield: 67.0%

3-chloro-benzenecarboperoxoic acid (937-14-4) + 3-chlorobenzoate (535-80-8) → m-chlorobenzoyl peroxide (845-30-7)

Guidance literature:

3-chlorobenzoate; With dicyclohexyl-carbodiimide; In dichloromethane; at 20 ℃; for 0.333333h;

3-chloro-benzenecarboperoxoic acid; In dichloromethane; at 20 ℃; for 4h;

DOI:10.1248/cpb.54.1412

upstream raw materials:

m-Chlorobenzoyl chloride

3-chloro-benzenecarboperoxoic acid

1-Iodododecane

2-phenyl-indole

Downstream raw materials:

α-tocopherylquinone

12-hydroxy-11-(3-chlorobenzoyloxy)-abieta-8,11,13-triene

Refernces

• 1、 Chen, Jiangfei,Zhu, Yan-Ping,Li, Jin-Heng,Wang, Qiu-An. "External-oxidant-free amino-benzoyloxylation of unactivated alkenes of unsaturated ketoximes with: O -benzoylhydroxylamines". supporting information. p. 5215 - 5218. Retrieved 2021/05/31.
• 2、 Li, Dong,Li, Jiale,Li, Juanjuan,Yuan, Songdong,Zhang, Qian. "An unprecedented cobalt-catalyzed selective aroylation of primary amines with aroyl peroxides". supporting information. . Retrieved 2020/09/16.