1-Phenylphenanthrene

Base Information

• Chemical Name: 1-Phenylphenanthrene
• CAS No.: 4325-76-2
• Molecular Formula: C20H14
• Molecular Weight: 254.331
• Hs Code.: 2902909090
• DSSTox Substance ID: DTXSID4075247
• Nikkaji Number: J1.554.011G
• Wikidata: Q82003256
• Mol file: 4325-76-2.mol

Synonyms:1-PHENYLPHENANTHRENE;Phenanthrene, 1-phenyl-;4325-76-2;phenylphenanthrene;-Phenyl phenanthrene;DTXSID4075247;RKLROMDZXDQSDF-UHFFFAOYSA-N;AB-131/42301021

Chemical Property of 1-Phenylphenanthrene

Chemical Property:

• Vapor Pressure: 3.05E-07mmHg at 25°C
• Boiling Point: 431.3°Cat760mmHg
• Flash Point: 207.8°C
• PSA: 0.00000
• Density: 1.14g/cm³
• LogP: 5.66000
• XLogP3: 6
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 1
• Exact Mass: 254.109550447
• Heavy Atom Count: 20
• Complexity: 314

Purity/Quality:

95% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)C2=CC=CC3=C2C=CC4=CC=CC=C43

Technology Process of 1-Phenylphenanthrene

There total 25 articles about 1-Phenylphenanthrene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

2-(2-methoxyethenyl)-1,3-diphenylbenzene → 1-phenyl phenanthrene (4325-76-2)

Guidance literature:

With bismuth(lll) trifluoromethanesulfonate; In 1,2-dichloro-ethane; at 25 ℃; for 0.5h; Inert atmosphere; Schlenk technique;

DOI:10.1021/ol5018273

Reference yield: 96.0%

2-iodobiphenyl (2113-51-1) + bicyclo[2.2.1]hepta-2,5-diene (121-46-0) + 2-bromobenzoic-acid (88-65-3) → 1-phenyl phenanthrene (4325-76-2)

Guidance literature:

With palladium diacetate; caesium carbonate; tricyclohexylphosphine; In 1,4-dioxane; at 130 ℃; for 18h; Schlenk technique; Sealed tube; Inert atmosphere;

DOI:10.1002/anie.201703551

Reference yield: 88.0%

2-iodobiphenyl (2113-51-1) + bicyclo[2.2.1]hepta-2,5-diene (121-46-0) + 2-bromobenzoic acid chloride (7154-66-7) → 1-phenyl phenanthrene (4325-76-2)

Guidance literature:

With palladium diacetate; caesium carbonate; triphenylphosphine; In N,N-dimethyl-formamide; at 105 ℃; for 10h; Inert atmosphere;

DOI:10.3762/bjoc.15.26

upstream raw materials:

(+/-)-1-Hydroxy-1-phenyl-1.2.3.4-tetrahydro-phenanthren

1-(4-phenyl-butyl)-naphthalene

1-Phenyl-1,2,3,9,10,10a-hexahydro-[3]phenanthrol

1-phenyl-3,4-dihydro-phenanthrene

Downstream raw materials:

1-phenyl-dibenzo[a,c]phenazine

8-phenyl-benz[de]anthracen-7-one

1-phenyl-phenanthrene-9,10-dione