4-Fluoro-3-phenoxybenzaldehyde

Base Information

• Chemical Name: 4-Fluoro-3-phenoxybenzaldehyde
• CAS No.: 68359-57-9
• Molecular Formula: C13H9FO2
• Molecular Weight: 216.212
• Hs Code.: 29130000
• European Community (EC) Number: 269-856-2
• DSSTox Substance ID: DTXSID0073611
• Nikkaji Number: J349.364D
• Wikidata: Q72475593
• Mol file: 68359-57-9.mol

Synonyms:4-Fluoro-3-phenoxybenzaldehyde;68359-57-9;Benzaldehyde, 4-fluoro-3-phenoxy-;4-fluoro-3-(phenoxy)benzaldehyde;EINECS 269-856-2;4-Fluoro-3-phenoxy-benzaldehyde;2-Fluoro-5-formyldiphenyl Ether;m-phenoxy-p-fluorobenzaldehyde;3-phenoxy-4fluorobenzaldehyde;SCHEMBL920233;3-phenoxy-4-fluorobenzaldehyde;3-phenoxy-4-fluoro-benzaldehyde;DTXSID0073611;JDICMOLUAHZVDS-UHFFFAOYSA-;AMY3643;BBL029236;MFCD01318148;STL374090;4-Fluoro-3-phenoxybenzaldehyde, 97%;AKOS000113557;CS-W014853;PS-7930;TRIETHYLSULFONIUMTETRAFLUOROBORATE;AC-15265;F0564;FT-0618492;D87649;W-104678

Chemical Property of 4-Fluoro-3-phenoxybenzaldehyde

Chemical Property:

• Appearance/Colour: Light yellowish liquid.
• Vapor Pressure: 0.000327mmHg at 25°C
• Refractive Index: n20/D 1.5830(lit.)
• Boiling Point: 320 °C at 760 mmHg
• Flash Point: 142.5 °C
• PSA: 26.30000
• Density: 1.229 g/cm³
• LogP: 3.43050
• Storage Temp.: under inert gas (nitrogen or Argon) at 2-8°C
• XLogP3: 3
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 3
• Exact Mass: 216.05865769
• Heavy Atom Count: 16
• Complexity: 226

Purity/Quality:

99% ^*data from raw suppliers

4-Fluoro-3-phenoxybenzaldehyde ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xn; N
• Hazard Codes: Xn,N
• Statements: 22-51/53
• Safety Statements: 61

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: C1=CC=C(C=C1)OC2=C(C=CC(=C2)C=O)F
• Uses: 4-Fluoro-3-phenoxybenzaldehyde is a reactant in the preparation of ring-disubstituted propyl cyano(phenyl)propenoates which are then used as copolymers with styrene.

Technology Process of 4-Fluoro-3-phenoxybenzaldehyde

There total 5 articles about 4-Fluoro-3-phenoxybenzaldehyde which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

→ 4-fluoro-3-phenoxybenzaldehyde (68359-57-9)

Guidance literature:

Reference yield:

cis-α-cyano-3-phenoxy-4-fluoro-benzyl-2,2-dimethyl-3-(2-chlorovinyl)cyclopropane-carboxylate → 3-Methylbutenoic acid (541-47-9) + 3-(2-chlorovinyl)-2,2-dimethylcyclopropane-carboxylic acid (60310-82-9) + 4-fluoro-3-phenoxybenzaldehyde (68359-57-9) + C8H11ClO + 2-(4-fluoro-3-phenoxyphenyl)-2-hydroxyethanenitrile (76783-44-3) + 4-fluoro-3-phenoxy benzoic acid (77279-89-1)

Guidance literature:

In hexane; for 17h; UV-irradiation;

DOI:10.1021/jf103908d

Reference yield:

cyfluthrin (68359-37-5,1820573-27-0,80850-08-4,85782-82-7) → 4-fluoro-3-phenoxybenzaldehyde (68359-57-9) + 3-(2,2-dichlorovinyl)-2,2-dimethylcyclopropanecarboxylic acid (55701-05-8)

Guidance literature:

With sodium hydroxide; In methanol; for 2h; Heating;

DOI:10.1007/s00128-007-9018-9

upstream raw materials:

cyfluthrin

4-fluoro-3-phenoxybenzyl bromide

1-Nitropropane

4-fluoro-3-phenoxy-benzaldehyde ethyleneacetal

Downstream raw materials:

1-(4-Fluoro-3-phenoxyphenyl)-4-(4-ethoxyphenyl)-4-methylpent-1-ene-3-one

4-fluoro-3-phenoxy benzoic acid

1-(4-fluoro-3-phenoxyphenyl)-2-propen-1-ol

3'-phenoxy-4'-fluoro-benzyl 2,2-dimethyl-3-(2,2-dichlorovinyl)-cyclopropane-carboxylate

Refernces

• 1、 Mukherjee,Gopal,Mathur. "Behavior of β-cyfluthrin after foliar application on chickpea (cicer aretinium L. ) and pigeon pea (cajanus cajan L.)". . p. 76 - 80. Retrieved 2008/02/02.
• 2、 -. "Preparation of 4-fluoro-3-phenoxy-benzal-dehyde acetals and intermediates therefor". . . Retrieved 2008/06/13.