(2-Azidoethoxy)(tert-butyl)dimethylsilane

Base Information

Chemical Name:(2-Azidoethoxy)(tert-butyl)dimethylsilane
CAS No.:113274-21-8
Molecular Formula:C8H19N3OSi
Molecular Weight:201.34100
Hs Code.:
DSSTox Substance ID:DTXSID00554477
Wikidata:Q82435485
Mol file:113274-21-8.mol

Synonyms:(2-Azidoethoxy)(tert-butyl)dimethylsilane;113274-21-8;2-azidoethoxy-tert-butyl-dimethylsilane;MFCD22423155;Silane, (2-azidoethoxy)(1,1-dimethylethyl)dimethyl-;C8H19N3OSi;DTXSID00554477;FWOURPSKAHEJOB-UHFFFAOYSA-N;AC1055;AKOS024257886;(2-Azidoethoxy)(t-butyl)dimethylsilane;CS-11438;SY021080;1-azido-2-(tert-butyldimethylsiloxy)ethane;1-azido-2-(tertbutyl-dimethylsiloxy)ethane

Suppliers and Price of (2-Azidoethoxy)(tert-butyl)dimethylsilane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

AK Scientific
(2-Azidoethoxy)(tert-butyl)dimethylsilane
5g
$ 546.00

AK Scientific
(2-Azidoethoxy)(tert-butyl)dimethylsilane
1g
$ 257.00

Total 9 raw suppliers

Chemical Property of (2-Azidoethoxy)(tert-butyl)dimethylsilane

Chemical Property:

PSA：58.98000
LogP:2.77126
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:5
Exact Mass:201.129738772
Heavy Atom Count:13
Complexity:204

Purity/Quality:

95%-99%min ^*data from raw suppliers

(2-Azidoethoxy)(tert-butyl)dimethylsilane ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(C)(C)[Si](C)(C)OCCN=[N+]=[N-]

Technology Process of (2-Azidoethoxy)(tert-butyl)dimethylsilane

There total 2 articles about (2-Azidoethoxy)(tert-butyl)dimethylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.7%

: 1517-05-1
2-azidoethanol

: 18162-48-6
tert-butyldimethylsilyl chloride

: 113274-21-8
1-azido-2-(tert-butyldimethylsiloxy)ethane

Guidance literature:: With 1H-imidazole; In N,N-dimethyl-formamide; at 40 ℃; for 24h;
DOI:10.1021/jo00242a022

Reference yield:

: 288-32-4
1H-imidazole

: 18162-48-6
tert-butyldimethylsilyl chloride

: 113274-21-8
1-azido-2-(tert-butyldimethylsiloxy)ethane

Guidance literature:: In water; N,N-dimethyl-formamide;

Reference yield: 89.0%

: (R_a)-methyl 3-(dimethyl(phenyl)silyl)hexa-3,4-dienoate

: 113274-21-8
1-azido-2-(tert-butyldimethylsiloxy)ethane

: 6630-33-7
ortho-bromobenzaldehyde

: 1204508-56-4
methyl (5S,6R)-6-(2-azidoethoxy)-6-(2-bromophenyl)-5-methylhex-3-ynoate

Guidance literature:: With trimethylsilyl trifluoromethanesulfonate; In propiononitrile; at -78 ℃; for 12h; optical yield given as %de; Inert atmosphere;
DOI:10.1021/ol902681t