2-Azido-5-methylbenzaldehyde

Base Information

Chemical Name:2-Azido-5-methylbenzaldehyde
CAS No.:113302-66-2
Molecular Formula:C8H7N3O
Molecular Weight:161.163
Hs Code.:
DSSTox Substance ID:DTXSID60555607
Wikidata:Q82437003

Synonyms:2-Azido-5-methylbenzaldehyde;113302-66-2;2-Azido-5-methyl-benzaldehyde;DTXSID60555607

Suppliers and Price of 2-Azido-5-methylbenzaldehyde

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 2-Azido-5-methylbenzaldehyde

Chemical Property:

XLogP3:2.7
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:2
Exact Mass:161.058911855
Heavy Atom Count:12
Complexity:210

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC1=CC(=C(C=C1)N=[N+]=[N-])C=O

Technology Process of 2-Azido-5-methylbenzaldehyde

There total 2 articles about 2-Azido-5-methylbenzaldehyde which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

: 113302-83-3
(2-azido-5-methylphenyl)methanol

: 113302-66-2
2-azido-5-methylbenzaldehyde

Guidance literature:: With pyridinium chlorochromate; In dichloromethane; for 1.5h; Ambient temperature;
DOI:10.1021/jo00244a038

Reference yield:

: 34897-84-2
2-amino-5-methylbenzyl alcohol

: 113302-66-2
2-azido-5-methylbenzaldehyde

Guidance literature:: Multi-step reaction with 2 steps

1: 1.) aq. HCl, NaNO₂, 2.) NaN₃ / 1.) 0 deg C, 1 h, 2.) from 5 deg C to RT

2: 83 percent / pyridinium chlorochromate / CH₂Cl₂ / 1.5 h / Ambient temperature

With hydrogenchloride; sodium azide; pyridinium chlorochromate; sodium nitrite; In dichloromethane;
DOI:10.1021/jo00244a038