Stannane, (1,2-ethanediyldi-2,1-phenylene)bis[trimethyl-

Base Information

Chemical Name:Stannane, (1,2-ethanediyldi-2,1-phenylene)bis[trimethyl-
CAS No.:113419-97-9
Molecular Formula:C₂₀H₃₀Sn₂
Molecular Weight:507.878
Hs Code.:

Synonyms:

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Chemical Property of Stannane, (1,2-ethanediyldi-2,1-phenylene)bis[trimethyl-

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Technology Process of Stannane, (1,2-ethanediyldi-2,1-phenylene)bis[trimethyl-

There total 2 articles about Stannane, (1,2-ethanediyldi-2,1-phenylene)bis[trimethyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

: 1066-45-1
trimethyltin(IV)chloride

: 113419-93-5
BrMgC₆H₄CH₂CH₂C₆H₄MgBr

: 113419-97-9
1,2-bis(2-trimethylstannylphenyl)ethane

Guidance literature:: In tetrahydrofuran; a suspn. of Grignard compound in THF was added at room temp. under nitrogen to a THF soln. of Me3SnCl, mixt. was stirred for 1 h; satd. aq. NH4Cl was added, aq. layer was extd. with Et2O, org. fractions were combined, dried, evapd., residue was purified by preparative GLC; high-resolution MS data;
DOI:10.1016/0022-328X(87)80301-7

Reference yield:

: 1066-45-1
trimethyltin(IV)chloride

: 578-51-8
2-bromobenzylchloride

: 7439-95-4
magnesium

: 113419-96-8
1-trimethylstannyl-2-((trimethylstannyl)methyl)benzene

: 113419-97-9
1,2-bis(2-trimethylstannylphenyl)ethane

: 113419-95-7
(CH₃)3SnCH₂C₆H₄C₆H₄CH₂Sn(CH₃)3

: 113419-94-6
(CH₃)3SnC₆H₄CH₂C₆H₄CH₂Sn(CH₃)3

: 105858-66-0
1,2-dihydro-1-magnesabenzocyclobutene

Guidance literature:: With ethylene dibromide; In tetrahydrofuran; Mg and (CH2Br)2 in THF were stirred for 15 min under nitrogen, THF soln. of 2-BrC6H4CH2Cl was added during 4 h, mixt. was stirred for 3 h; THF was added, soln. filtered through a coarse glass-filter to remove the residual Mg, filtrate was allowed to settle and decanted leaving magnesacycle as a ppt., soln. was derivatized with Me3SiCl and analyzed by GC-MS;
DOI:10.1016/0022-328X(87)80301-7