Stannane, trimethyl[2-[(trimethylstannyl)methyl]phenyl]-

Base Information

Chemical Name:Stannane, trimethyl[2-[(trimethylstannyl)methyl]phenyl]-
CAS No.:113419-96-8
Molecular Formula:C₁₃H₂₄Sn₂
Molecular Weight:417.754
Hs Code.:
Mol file:113419-96-8.mol

Synonyms:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Stannane, trimethyl[2-[(trimethylstannyl)methyl]phenyl]-

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:: SDS file from LookChem

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Technology Process of Stannane, trimethyl[2-[(trimethylstannyl)methyl]phenyl]-

There total 10 articles about Stannane, trimethyl[2-[(trimethylstannyl)methyl]phenyl]- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

: 1066-45-1
trimethyltin(IV)chloride

: 105858-66-0
1,2-dihydro-1-magnesabenzocyclobutene

: 113419-96-8
1-trimethylstannyl-2-((trimethylstannyl)methyl)benzene

Guidance literature:: In tetrahydrofuran; a suspn. of magnesacycle in THF was added at room temp. under nitrogen to a THF soln. of Me3SnCl, mixt. was stirred for 1 h; satd. aq. NH4Cl was added, aq. layer was extd. with Et2O, org. fractions were combined, dried, evapd., residue was purified by preparative GLC; elem. anal., high-resolution MS data;
DOI:10.1016/0022-328X(87)80301-7

Reference yield: 45.0%

: 1066-45-1
trimethyltin(IV)chloride

: 3433-80-5
1-Bromo-2-bromomethyl-benzene

: 113419-96-8
1-trimethylstannyl-2-((trimethylstannyl)methyl)benzene

Guidance literature:: With magnesium; ethylene dibromide; In tetrahydrofuran; inert atmosphere, activation of Mg with ethylene bromide in THF, addn. of THF and a further portion of ethylene bromide, reflux, addn. of soln. of bromobenzyl bromide and soln. of (CH3)3SnCl to the boiling soln., reflux (6 h); saturated aq. NH4Cl, extn. (Et2O), washing of extracts (water), drying (Na2SO4), concn. (reduced pressure), distillation (89-92°C, 0.1 Torr);
DOI:10.1002/(SICI)1099-0682(199806)1998:6<761::AID-EJIC761>3.0.CO;2-1

Reference yield: 34.0%

: 54031-00-4
1-bromo-2-((trimethylstannyl)methyl)benzene

: 1529-47-1
chlorotrimethylgermane

: 113419-96-8
1-trimethylstannyl-2-((trimethylstannyl)methyl)benzene

: 114198-52-6
1-trimethylgermyl-2-((trimethylstannyl)methyl)benzene

: 113419-98-0
1-trimethylgermyl-2-trimethylgermylmethylbenzene

: 114198-53-7
1-(trimethylgermyl)methyl-2-(trimethylstannyl)benzene

Guidance literature:: With Mg; NH₄Cl; In tetrahydrofuran; using high-vac. techniques; mixt. of C6H4(Br)(CH2SnMe3), Mg in THF stirred at 60°C; after 24 h Me3GeCl added; Et2O and satd. NH4Cl added; org. fraction sepd.; aq. fraction extd. (Et2O); org. fractions combined; dried (MgSO4); filtered; evapd. to dryness;analyzed by NMR; isolated by chromy.;
DOI:10.1021/om011083a