Tetraphenylarsonium chloride hydrochloride

Base Information

Chemical Name:Tetraphenylarsonium chloride hydrochloride
CAS No.:73003-83-5
Molecular Formula:C24H21AsCl2
Molecular Weight:455.258
Hs Code.:
European Community (EC) Number:244-144-4,277-208-5
DSSTox Substance ID:DTXSID20890324

Synonyms:1-(3-tertbutyl-2-hydroxy-5-methoxyphenyl)-3-(3-pyridylmethyl)urea hydrochloride;T 0162;T-0162;T0162

Suppliers and Price of Tetraphenylarsonium chloride hydrochloride

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 6 raw suppliers

Chemical Property of Tetraphenylarsonium chloride hydrochloride

Chemical Property:

Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:4
Exact Mass:454.023626
Heavy Atom Count:27
Complexity:301

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

Chemical Classes:Metals -> Arsenic Compounds, Organic
Canonical SMILES:C1=CC=C(C=C1)[As+](C2=CC=CC=C2)(C3=CC=CC=C3)C4=CC=CC=C4.Cl.[Cl-]

Technology Process of Tetraphenylarsonium chloride hydrochloride

There total 1 articles about Tetraphenylarsonium chloride hydrochloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

: 108-86-1,52753-63-6
bromobenzene

: 1153-05-5,856568-31-5
triphenylarsineoxide

: 73003-83-5
tetraphenylarsonium chloride hydrochloride

Guidance literature:: bromobenzene; With iodine; magnesium; In diethyl ether; for 2h; Inert atmosphere; Schlenk technique; Reflux;

triphenylarsineoxide; In diethyl ether; toluene; at 40 ℃; for 15h; Inert atmosphere; Schlenk technique;

With hydrogenchloride; In water; at 100 ℃; for 1h;
DOI:10.1016/j.jfluchem.2017.03.014

Reference yield: 82.0%

: Na[Co₃(CPh)(CO)8(PPh₂(C₆H₄SO₃-m))]

: 73003-83-5
tetraphenylarsonium chloride hydrochloride

: AsPh₄[Co₃(CPh)(CO)8(PPh₂(C₆H₄SO₃-m))] * 3 H₂O

Guidance literature:: In hydrogenchloride; N2-atmosphere; pptn. on addn. of aq. AsPh4Cl to Co-complex (in 4 M HCl, pptn.); decantation, washing (H2O), drying (vac.); elem. anal.;
DOI:10.1039/DT9940002821

Reference yield: 70.0%

: 61989-21-7
carbonyldichloro(methanol)bis(triphenylphosphine)ruthenium(II)

: 73003-83-5
tetraphenylarsonium chloride hydrochloride

: tetraphenylarsonium carbonyl(trichloro)bis(triphenylphosphine)ruthenate(II)-acetone (1/1)

Guidance literature:: With triphenylphosphine; In acetone; two-fold excess of Ph4AsCl*HCl, shaking for 4 h (pptn.); filtration, washing (water, MeOH, Et2O), drying (vac., 40°C); elem. anal.;
DOI:10.1039/DT9760002121