Technology Process of Silane,
[(2-chloro-1,1-dioxidothiacycloundeca-3,9-diyne-6,7-diyl)bis(methylene
oxy)]bis[(1,1-dimethylethyl)diphenyl-
There total 10 articles about Silane,
[(2-chloro-1,1-dioxidothiacycloundeca-3,9-diyne-6,7-diyl)bis(methylene
oxy)]bis[(1,1-dimethylethyl)diphenyl- which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
3-chloro-benzenecarboperoxoic acid;
In
dichloromethane;
for 18h;
DOI:10.1021/ja00229a068
- Guidance literature:
-
Multi-step reaction with 8 steps
1: PPh3 / CH2Cl2 / 8 h / 0 - 25 °C
2: 74 percent / n-BuLi / tetrahydrofuran / 1.25 h / -78 - 0 °C
3: 97 percent / DIBAL / CH2Cl2 / 6.5 h / -78 °C
4: P(oct)3, CBr4 / diethyl ether / 1 h / 0 °C
5: 58 percent / Na2S*9H2O / ethanol; H2O / 1.5 h / 78 °C
6: 90 percent / mCPBA / CH2Cl2 / 0.5 h / -30 °C
7: 79 percent / SO2Cl2/pyridine / CH2Cl2 / 0.17 h / -78 °C
8: 99 percent / mCPBA / CH2Cl2 / 18 h
With
pyridine; sodium sulfide; n-butyllithium; sulfuryl dichloride; carbon tetrabromide; TOP; diisobutylaluminium hydride; 3-chloro-benzenecarboperoxoic acid; triphenylphosphine;
In
tetrahydrofuran; diethyl ether; ethanol; dichloromethane; water;
DOI:10.1021/ja00229a068
- Guidance literature:
-
Multi-step reaction with 7 steps
1: 74 percent / n-BuLi / tetrahydrofuran / 1.25 h / -78 - 0 °C
2: 97 percent / DIBAL / CH2Cl2 / 6.5 h / -78 °C
3: P(oct)3, CBr4 / diethyl ether / 1 h / 0 °C
4: 58 percent / Na2S*9H2O / ethanol; H2O / 1.5 h / 78 °C
5: 90 percent / mCPBA / CH2Cl2 / 0.5 h / -30 °C
6: 79 percent / SO2Cl2/pyridine / CH2Cl2 / 0.17 h / -78 °C
7: 99 percent / mCPBA / CH2Cl2 / 18 h
With
pyridine; sodium sulfide; n-butyllithium; sulfuryl dichloride; carbon tetrabromide; TOP; diisobutylaluminium hydride; 3-chloro-benzenecarboperoxoic acid;
In
tetrahydrofuran; diethyl ether; ethanol; dichloromethane; water;
DOI:10.1021/ja00229a068
