Benzenethiol, 2-(triphenylsilyl)-

Base Information

Chemical Name:Benzenethiol, 2-(triphenylsilyl)-
CAS No.:117526-60-0
Molecular Formula:C24H20SSi
Molecular Weight:368.574
Hs Code.:
DSSTox Substance ID:DTXSID90477065
Nikkaji Number:J692.310K
Mol file:117526-60-0.mol

Synonyms:Benzenethiol, 2-(triphenylsilyl)-;117526-60-0;DTXSID90477065

Suppliers and Price of Benzenethiol, 2-(triphenylsilyl)-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 1 raw suppliers

Chemical Property of Benzenethiol, 2-(triphenylsilyl)-

Chemical Property:

Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:4
Exact Mass:368.10549835
Heavy Atom Count:26
Complexity:372

Purity/Quality:: 99.90% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1=CC=C(C=C1)[Si](C2=CC=CC=C2)(C3=CC=CC=C3)C4=CC=CC=C4S

Technology Process of Benzenethiol, 2-(triphenylsilyl)-

There total 1 articles about Benzenethiol, 2-(triphenylsilyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 76-86-8
Triphenylsilyl chloride

: 108-98-5
thiophenol

: 117526-60-0
2-(triphenylsilyl)benzenethiol

Guidance literature:: With n-butyllithium; Yield given. Multistep reaction; 1.) cyclohexane, 25 deg C, 24 h, 2.) THF;
DOI:10.1021/ja00184a039

Reference yield: 88.0%

: 15318-33-9,16353-77-8,13938-94-8
chlorocarbonylbis(triphenylphosphine)rhodium(I)

: 117526-60-0
2-(triphenylsilyl)benzenethiol

: [Rh2(μ-2-triphenylsilylbenzenethiolate)2(CO)2(PPh3)2]

Guidance literature:: With Et₃N; In methanol; N2-atmosphere; addn. of 4 equiv. of thiol and triethylamine to Rh-complex, refluxing for 2 h (pptn.); immediate collection (filtration), washing (MeOH, ether); elem. anal.;
DOI:10.1039/DT9950003143

Reference yield: 86.0%

: 10199-34-5,14056-88-3,15604-36-1
cis-dichlorobis(triphenylphosphine)platinum(II)

: 117526-60-0
2-(triphenylsilyl)benzenethiol

: 910110-67-7
z-[Pt(PPh₃)2(C₆H₄S-2-SiPh₃)Cl]

Guidance literature:: With triethylamine; In dichloromethane; (under N2, Schlenk); soln. of ligand and N(CH2CH3)3 in CH2Cl2 added dropwise to CH2Cl2 soln. of Pt-complex, stirred overnight; filtered, solvent evapd. under vac.; elem. anal.;
DOI:10.1016/j.ica.2006.05.018