Tributyl(5-methyl-1-phenylhex-4-EN-3-YL)stannane

Base Information

Chemical Name:Tributyl(5-methyl-1-phenylhex-4-EN-3-YL)stannane
CAS No.:117785-55-4
Molecular Formula:C25H44Sn
Molecular Weight:463.334
Hs Code.:
DSSTox Substance ID:DTXSID70552001
Mol file:117785-55-4.mol

Synonyms:117785-55-4;DTXSID70552001;TRIBUTYL(5-METHYL-1-PHENYLHEX-4-EN-3-YL)STANNANE

Suppliers and Price of Tributyl(5-methyl-1-phenylhex-4-EN-3-YL)stannane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 1 raw suppliers

Chemical Property of Tributyl(5-methyl-1-phenylhex-4-EN-3-YL)stannane

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:14
Exact Mass:464.246504
Heavy Atom Count:26
Complexity:339

Purity/Quality:: 99.90% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CCCC[Sn](CCCC)(CCCC)C(CCC1=CC=CC=C1)C=C(C)C

Technology Process of Tributyl(5-methyl-1-phenylhex-4-EN-3-YL)stannane

There total 1 articles about Tributyl(5-methyl-1-phenylhex-4-EN-3-YL)stannane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 117785-42-9
2-methyl-6-phenyl-4-(phenylthio)hex-2-ene

: 4226-01-1
tri-n-butyltin lithium

: 117785-55-4
2-methyl-4-(tributylstannyl)-6-phenyl-2-hexene

Guidance literature:: With copper(I) bromide; In tetrahydrofuran; N,N,N,N,N,N-hexamethylphosphoric triamide; addn. of a soln. of tributylstannyllithium in THF to a mixt. of the thiobutene and CuBr in THF/HMPT under Ar with stirring; quenching with phosphate buffer soln. (pH 7), extn. with CH2Cl2, drying over Na2SO4, concg. under reduced pressure, chromy. on silica gel (hexane), IR, NMR, 67 to 72 % yield at various conditions;
DOI:10.1246/cl.1987.1967