Digermoxane, 1,1,3,3-tetramethyl-1,3-diphenyl-

Base Information

• Chemical Name: Digermoxane, 1,1,3,3-tetramethyl-1,3-diphenyl-
• CAS No.: 119405-78-6
• Molecular Formula: C₁₆H₂₂Ge₂O
• Molecular Weight: 375.53
• DSSTox Substance ID: DTXSID80587223
• Wikidata: Q82479591
• Mol file: 119405-78-6.mol

Synonyms:119405-78-6;Digermoxane, 1,1,3,3-tetramethyl-1,3-diphenyl-;[dimethyl(phenyl)germyl]oxy-dimethyl-phenylgermane;DTXSID80587223;1,1,3,3-Tetramethyl-1,3-diphenyldigermoxane

Chemical Property of Digermoxane, 1,1,3,3-tetramethyl-1,3-diphenyl-

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 4
• Exact Mass: 376.0103189
• Heavy Atom Count: 19
• Complexity: 249

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C[Ge](C)(C1=CC=CC=C1)O[Ge](C)(C)C2=CC=CC=C2

Technology Process of Digermoxane, 1,1,3,3-tetramethyl-1,3-diphenyl-

There total 3 articles about Digermoxane, 1,1,3,3-tetramethyl-1,3-diphenyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 7.0%

phenylpentamethyldigermane (32284-96-1) + 2,3-dimethyl-buta-1,3-diene (513-81-5) → dimethylphenyldigermanoxane (119405-78-6) + o-(trimethylgermyl)(2,3-dimethyl-3-butenyl)dimethylgermylbenzene + 1,1,3,4-tetramethyl-1-germacyclopenta-3-ene (5764-66-9)

Guidance literature:

In cyclohexane; Irradiation (UV/VIS); irradiation of catenate in cyclohexane containing an excess of 2,3-dimethylbutadiene with a 110 W low-pressure Hg arc lamp at room temp. under Ar for 1-4 h; identification by GC and GC-MS;

DOI:10.1016/0022-328X(91)86036-P

Reference yield: 1.0%

phenylpentamethyldigermane (32284-96-1) → (C6H5)(CH3)2GeGe(CH3)2Ge(CH3)3 + dimethylphenyldigermanoxane (119405-78-6) + 1,3-diphenylhexamethyltrigermane (22702-73-4) + octamethyltrigermane (1066-63-3) + 1,1,2,2-tetramethyl-1,2-diphenyldigermane (22702-72-3)

Guidance literature:

With methanol; In benzene; Irradiation (UV/VIS); irradiation of catenate in benzene containing an excess of methanol with a 110 W low-pressure Hg arc lamp at room temp. under Ar for 1-4 h; identification by GC and GC-MS;

DOI:10.1016/0022-328X(91)86036-P

Reference yield:

(CH3)2C6H5GeOOOH (883907-65-1) → dimethylphenyldigermanoxane (119405-78-6)

Guidance literature:

In further solvent(s); keeping a soln. of germanium compd. in t-butyl methyl ether at -40°C; Kinetics;

DOI:10.1021/ja058065v

upstream raw materials:

phenylpentamethyldigermane

2,3-dimethyl-buta-1,3-diene

(CH₃)2C₆H₅GeOOOH

Downstream raw materials:

phenyldimethylchlorogermane