Technology Process of Trigermane, 1,1,2,2,3,3-hexamethyl-1,3-diphenyl-
There total 4 articles about Trigermane, 1,1,2,2,3,3-hexamethyl-1,3-diphenyl- which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
phenyldimethylchlorogermane;
With
lithium;
In
tetrahydrofuran;
at 0 ℃;
for 0.25h;
Inert atmosphere;
With
magnesium bromide;
at 20 ℃;
for 0.5h;
Schlenk technique;
Inert atmosphere;
dichlorodimethylgermanium;
In
tetrahydrofuran;
at 0 ℃;
Inert atmosphere;
Schlenk technique;
DOI:10.1021/jacs.5b08155
- Guidance literature:
-
With
methanol;
In
benzene;
Irradiation (UV/VIS); irradiation of catenate in benzene containing an excess of methanol with a 110 W low-pressure Hg arc lamp at room temp. under Ar for 1-4 h; identification by GC and GC-MS;
DOI:10.1016/0022-328X(91)86036-P
- Guidance literature:
-
Multi-step reaction with 2 steps
1.1: trifluorormethanesulfonic acid / dichloromethane / -78 - 20 °C
1.2: 1.5 h / 0 - 20 °C / Inert atmosphere
2.1: lithium / tetrahydrofuran / 0.25 h / 0 °C / Inert atmosphere
2.2: 0.5 h / 20 °C / Schlenk technique; Inert atmosphere
2.3: 0 °C / Inert atmosphere; Schlenk technique
With
trifluorormethanesulfonic acid; lithium;
In
tetrahydrofuran; dichloromethane;
DOI:10.1021/jacs.5b08155
