Silane, [(1-cyclohexylethenyl)oxy]trimethyl-

Base Information

• Chemical Name: Silane, [(1-cyclohexylethenyl)oxy]trimethyl-
• CAS No.: 119612-85-0
• Molecular Formula: C11H22OSi
• Molecular Weight: 198.381
• DSSTox Substance ID: DTXSID60450062
• Nikkaji Number: J1.123.735E
• Wikidata: Q82269632
• Mol file: 119612-85-0.mol

Synonyms:Silane, [(1-cyclohexylethenyl)oxy]trimethyl-;119612-85-0;DTXSID60450062;Trimethyl(1-cyclohexylethenyloxy)silane

Chemical Property of Silane, [(1-cyclohexylethenyl)oxy]trimethyl-

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 3
• Exact Mass: 198.143991855
• Heavy Atom Count: 13
• Complexity: 175

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: C[Si](C)(C)OC(=C)C1CCCCC1

Technology Process of Silane, [(1-cyclohexylethenyl)oxy]trimethyl-

There total 4 articles about Silane, [(1-cyclohexylethenyl)oxy]trimethyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

chloro-trimethyl-silane (75-77-4) + Cyclohexyl methyl ketone (823-76-7) → {[1-cyclohexylethenyl]oxy}trimethylsilane (119612-85-0)

Guidance literature:

With lithium diisopropyl amide; In tetrahydrofuran; 1.) -25 deg C, 10 min, 2.) r.t., 2.5 h;

DOI:10.1021/jo00121a029

Reference yield: 84.0%

cyclohexanecarbaldehyde (2043-61-0) + diazomethyl-trimethyl-silane (18107-18-1) → {[1-cyclohexylethenyl]oxy}trimethylsilane (119612-85-0)

Guidance literature:

diazomethyl-trimethyl-silane; With n-butyllithium; In tetrahydrofuran; hexane; at -78 ℃; for 1h;

cyclohexanecarbaldehyde; With methanol; In tetrahydrofuran; hexane; at -78 ℃; for 0.833333h;

With dirhodium tetraacetate; In tetrahydrofuran; hexane; at -78 - 20 ℃; Further stages.;

DOI:10.1021/ja027061c

Reference yield:

cyclohexanecarbaldehyde (2043-61-0) + diazomethyl-trimethyl-silane (18107-18-1) → {[(Z)-2-cyclohexylethenyl]oxy}trimethylsilane (177489-63-3) + {[(E)-2-cyclohexylethenyl]oxy}trimethylsilane (177489-62-2) + {[1-cyclohexylethenyl]oxy}trimethylsilane (119612-85-0)

Guidance literature:

With aluminum (III) chloride; In dichloromethane; at -30 ℃; for 0.0833333h; Reagent/catalyst; Solvent; Overall yield = 95 %; Inert atmosphere;

DOI:10.1002/chem.201203968

upstream raw materials:

Cyclohexyl methyl ketone

chloro-trimethyl-silane

cyclohexanecarbaldehyde

diazomethyl-trimethyl-silane

Downstream raw materials:

6-Cyclohexyl-3,3-dimethyl-2H-pyran-2,4(3H)-dion

(1-Cyclohexyl-cyclopropoxy)-trimethyl-silane

1-cyclohexyl-2-hydroxyethanone

vinylcyclohexane