Propylamine, N-benzylidene-

Base Information

• Chemical Name: Propylamine, N-benzylidene-
• CAS No.: 6852-55-7
• Molecular Formula: C10H13N
• Molecular Weight: 147.22
• Hs Code.: 2925290090
• NSC Number: 69424
• UNII: T2W67C4NZ6
• DSSTox Substance ID: DTXSID70290552
• Nikkaji Number: J1.553.922D,J113.896K
• Mol file: 6852-55-7.mol

Synonyms:Propylamine, N-benzylidene-;1-Propanamine, N-(phenylmethylene)-;1-phenyl-N-propylmethanimine;N-Propylbenzylideneimine;6852-55-7;N-Benzylidenepropylamine;T2W67C4NZ6;Benzylidene-propyl-amine;Propylamine, N-benzylidene-, (E)-;N-Benzylidenepropan-1-amine;UNII-T2W67C4NZ6;(N(E))-N-(Phenylmethylene)-1-propanamine;1-Propanamine, N-(phenylmethylene)-, (E)-;1-Propanamine, N-(phenylmethylene)-, (N(E))-;NSC 69424;NSC-69424;27845-48-3;N-(Phenylmethylidene)-1-propanamine;NSC69424;N-Propylbenzenemethanimine;NCIOpen2_000375;(E)-N-Propylphenylmethanimine;SCHEMBL5235095;SCHEMBL6289914;DTXSID70290552;N-(phenylmethylene)-1-propanamine;AKOS006346534;AKOS024332522

Chemical Property of Propylamine, N-benzylidene-

Chemical Property:

• Vapor Pressure: 0.131mmHg at 25°C
• Boiling Point: 225.1°Cat760mmHg
• Flash Point: 81.5°C
• PSA: 12.36000
• Density: 0.87g/cm³
• LogP: 2.51550
• XLogP3: 2.5
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 3
• Exact Mass: 147.104799419
• Heavy Atom Count: 11
• Complexity: 112

Purity/Quality:

99%min ^*data from raw suppliers

Benzylidene-propyl-amine ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCN=CC1=CC=CC=C1

Technology Process of Propylamine, N-benzylidene-

There total 23 articles about Propylamine, N-benzylidene- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

propylamine (107-10-8,42939-71-9) + benzaldehyde (100-52-7) → N-benzylidenepropylamine (6852-55-7)

Guidance literature:

In toluene; for 1h; Ambient temperature;

DOI:10.1002/jhet.5570330136

Reference yield: 99.0%

propylamine (107-10-8,42939-71-9) + benzyl alcohol (100-51-6,185532-71-2) → N-benzylidenepropylamine (6852-55-7)

Guidance literature:

With C₃₀H₂₄AgBr₄N₈⁽¹⁺⁾*AgBr₂^(1-); N-benzyl-trimethylammonium hydroxide; In toluene; at 20 ℃; for 12h; Molecular sieve; Schlenk technique;

DOI:10.1021/ol501353q

Reference yield: 75.0%

propylamine (107-10-8,42939-71-9) + 3-chloro-3-phenyl-3H-diazirine (4460-46-2) → N-benzylidenepropylamine (6852-55-7)

Guidance literature:

In hexane; at 25 ℃; for 7h; Irradiation;

DOI:10.1139/v94-250

upstream raw materials:

propylamine

benzaldehyde

N-methyl-N'-benzylidene-4-methylbenzenesulfonohydrazide

N-benzylidene tert-butylamine

Downstream raw materials:

N-Propyl-N-(α-chlorobenzyl)carbamoylchlorid

ethylpropylamine

10-Phenyl-9-propyl-9,11-diaza-bicyclo[6.2.1]undeca-1⁽¹⁰⁾,8⁽¹¹⁾-diene

N-benzylidene tert-butylamine

Refernces

• 1、 Ramachandran, P. Veeraraghavan,Choudhary, Shivani,Singh, Aman. "Trimethyl Borate-Catalyzed, Solvent-Free Reductive Amination". . p. 4274 - 4280. Retrieved 2021/03/09.
• 2、 Adhikary, Subhasis D.,Mandal, Debaprasad. "Polyoxometalate catalyzed imine synthesis: Investigation of mechanistic pathways". supporting information. . Retrieved 2020/05/25.