Bromotris(2-methyl-2-phenylpropyl)stannane

Base Information

• Chemical Name: Bromotris(2-methyl-2-phenylpropyl)stannane
• CAS No.: 1256-56-0
• Molecular Formula: C30H39BrSn
• Molecular Weight: 598.254
• DSSTox Substance ID: DTXSID10514224
• Wikidata: Q82374420
• Mol file: 1256-56-0.mol

Synonyms:1256-56-0;Bromotris(2-methyl-2-phenylpropyl)stannane;DTXSID10514224

Chemical Property of Bromotris(2-methyl-2-phenylpropyl)stannane

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 9
• Exact Mass: 598.12572
• Heavy Atom Count: 32
• Complexity: 481

Purity/Quality:

98%min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(C)(C[Sn](CC(C)(C)C1=CC=CC=C1)(CC(C)(C)C2=CC=CC=C2)Br)C3=CC=CC=C3

Technology Process of Bromotris(2-methyl-2-phenylpropyl)stannane

There total 5 articles about Bromotris(2-methyl-2-phenylpropyl)stannane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

6-Bromo-1-hexene (2695-47-8) + trineophyltin hydride (63353-12-8) → tris(2-methyl-2-phenylpropyl)stannane bromide (1256-56-0)

Guidance literature:

With 2,2'-azobis(isobutyronitrile); In toluene; byproducts: CH2CH(CH2)3CH3, C5H9CH3, C6H12; 6-bromo-1-hexene and azobisisobutyronitrile (catalyst) were added to soln. of Sn hydride in toluene under Ar; mixt. was refluxed for 3 h; distd.; chromd.;

DOI:10.1016/j.jorganchem.2005.11.020

Reference yield:

tetrakis(2-methyl-2-phenylpropyl)stannane (1262-78-8) + bromine (7726-95-6) → tris(2-methyl-2-phenylpropyl)stannane bromide (1256-56-0)

Guidance literature:

In tetrachloromethane; 1h reflux;

DOI:10.1021/ic50035a021

Reference yield:

tetrakis(2-methyl-2-phenylpropyl)stannane (1262-78-8) + hydrogen bromide (10035-10-6,12258-64-9) → tris(2-methyl-2-phenylpropyl)stannane bromide (1256-56-0)

Guidance literature:

In toluene; reflux, 7 h;

DOI:10.1021/ic50035a021

upstream raw materials:

tetrakis(2-methyl-2-phenylpropyl)stannane

bromine

6-Bromo-1-hexene

trineophyltin hydride

Downstream raw materials:

dineophyltin dichloride

tris(2-methyl-2-phenylpropyl)stannane iodide