Bromo(triphenyl)plumbane

Base Information

Chemical Name:Bromo(triphenyl)plumbane
CAS No.:894-06-4
Molecular Formula:C18H15BrPb
Molecular Weight:518.421
Hs Code.:
NSC Number:141819
DSSTox Substance ID:DTXSID20301208
Wikidata:Q82044877

Synonyms:bromo(triphenyl)plumbane;Triphenyllead bromide;894-06-4;Plumbane, bromotriphenyl-;NSC141819;Bromotriphenyllead(IV);SCHEMBL3132779;DTXSID20301208;MFCD00045007;AKOS024429206;NSC-141819

Suppliers and Price of Bromo(triphenyl)plumbane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 7 raw suppliers

Chemical Property of Bromo(triphenyl)plumbane

Chemical Property:

Vapor Pressure:9.04E-08mmHg at 25°C
Boiling Point:447.2°Cat760mmHg
Flash Point:224.3°C
Density:g/cm³
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:3
Exact Mass:518.01237
Heavy Atom Count:20
Complexity:240

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1=CC=C(C=C1)[Pb](C2=CC=CC=C2)(C3=CC=CC=C3)Br

Technology Process of Bromo(triphenyl)plumbane

There total 2 articles about Bromo(triphenyl)plumbane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 42.0%

: 506-68-3
bromocyane

: 3124-01-4
hexaphenyl diplumbane

: 10177-50-1
triphenyllead cyanide

: 894-06-4
triphenyl lead bromide

Guidance literature:: In tetrachloromethane; dropwise addn. of CNBr in CCl4 to stirred suspension of Pb2(C6H5)6 in CCl4 during at room temp.; refluxing; reaction time 2 h;; fractional crystn.; repeated recrystn.; m.p.;;
DOI:10.1016/S0277-5387(00)84419-8

Reference yield:

: 894-06-4
triphenyl lead bromide

Guidance literature:: Hexaphenyldiblei, 1.) KMnO4, 2.) HBr;
DOI:10.1016/S0022-328X(00)86330-5

Reference yield: 99.0%

: 58204-17-4
Roussin's red sodium salt

: 894-06-4
triphenyl lead bromide

: 79827-03-5
((C₆H₅)3PbS)2Fe₂(NO)4

Guidance literature:: In tetrahydrofuran; under N2, Ph3PbBr added to stirred soln. of Na(S2Fe2(NO)4)*8H2O in THF, stirred for 2 h; evapd. in vac., chromd. (SiO2, 20% CH2Cl2/pentane), evapd., recrystd. from CH2Cl2/pentane under N2; elem. anal.;