Plumbanecarbonitrile, triphenyl-

Base Information

• Chemical Name: Plumbanecarbonitrile, triphenyl-
• CAS No.: 10177-50-1
• Molecular Formula: C₁₉H₁₅NPb
• Molecular Weight: 464.535
• Mol file: 10177-50-1.mol

Synonyms:

Chemical Property of Plumbanecarbonitrile, triphenyl-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Plumbanecarbonitrile, triphenyl-

There total 2 articles about Plumbanecarbonitrile, triphenyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 54.0%

cyanogen iodide (506-78-5) + hexaphenyl diplumbane (3124-01-4) → triphenyllead cyanide (10177-50-1) + triphenyllead iodide (894-07-5)

Guidance literature:

In tetrachloromethane; dropwise addn. of CNI in CCl4 to stirred suspension of Pb2(C6H5)6 in CCl4 during 30 min at room temp.; refluxing for 30 min;; filtration, washing with ether, recrystn. from abs. alcohol yielded Pb(C6H5)3CN; concentrating filtrate and cooling yielded Pb(C6H5)3I; m.p.; IR spectroscopy;;

DOI:10.1016/S0277-5387(00)84419-8

Reference yield: 42.0%

bromocyane (506-68-3) + hexaphenyl diplumbane (3124-01-4) → triphenyllead cyanide (10177-50-1) + triphenyl lead bromide (894-06-4)

Guidance literature:

In tetrachloromethane; dropwise addn. of CNBr in CCl4 to stirred suspension of Pb2(C6H5)6 in CCl4 during at room temp.; refluxing; reaction time 2 h;; fractional crystn.; repeated recrystn.; m.p.;;

DOI:10.1016/S0277-5387(00)84419-8

upstream raw materials:

bromocyane

hexaphenyl diplumbane

cyanogen iodide