2-tert-butylfuMaronitrile

Base Information

• Chemical Name: 2-tert-butylfuMaronitrile
• CAS No.: 131079-29-3
• Molecular Formula: C8H10N2
• Molecular Weight: 134.17800
• Mol file: 131079-29-3.mol

Synonyms:cis-t-Butylmaleonitril;(Z)-2-tert-Butyl-but-2-enedinitrile;cis-1,2-dicyano-3,3-dimethyl-1-butene;2-(2,2-dimethylethyl)butenedinitrile;

Chemical Property of 2-tert-butylfuMaronitrile

Chemical Property:

• PSA: 47.58000
• LogP: 2.00606

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 2-tert-butylfuMaronitrile

There total 5 articles about 2-tert-butylfuMaronitrile which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 52.0%

cis-1,2-dibromine-3,3-dimethyl-1-butylene (99584-95-9) + copper(l) cyanide → 2-(2,2-dimethylethyl)butenedinitrile (131079-29-3,169309-80-2)

Guidance literature:

In N,N-dimethyl-formamide; for 4h; Reflux;

DOI:10.1039/c4dt00411f

Reference yield:

diethyl cyanomethyl phosphonate (50586-62-4) + copper(l) cyanide + pivaloyl chloride (3282-30-2) → 2-(2,2-dimethylethyl)butenedinitrile (131079-29-3,169309-80-2)

Guidance literature:

copper(l) cyanide; pivaloyl chloride; In tetrahydrofuran; at 130 ℃; for 24h; Inert atmosphere;

diethyl cyanomethyl phosphonate; With potassium tert-butylate; at 20 - 30 ℃; for 0.5h; Reagent/catalyst; Temperature; Inert atmosphere;

Reference yield:

tert-butylmercury iodide (89379-02-2) + 1,2-Dicyanoethylene (764-42-1) → 2-(2,2-dimethylethyl)butanedinitrile (75354-13-1) + t-butylmaleonitrile (131079-29-3,169309-80-2)

Guidance literature:

With potassium iodide; In dimethyl sulfoxide; at 35 - 40 ℃; for 23h; Title compound not separated from byproducts; Irradiation;

upstream raw materials:

cis-1,2-dibromine-3,3-dimethyl-1-butylene

3,3-Dimethylbut-1-yne

diethyl cyanomethyl phosphonate

pivaloyl chloride