Carbonic acid phenyl p-tolyl ester

Base Information

• Chemical Name: Carbonic acid phenyl p-tolyl ester
• CAS No.: 13183-20-5
• Molecular Formula: C14H12O3
• Molecular Weight: 228.24300
• Hs Code.: 2920909090
• Mol file: 13183-20-5.mol

Synonyms:phenyl-p-tolyl carbonate;Kohlensaeure-phenylester-p-tolylester;Carbonic acid,phenyl p-tolyl ester;Phenyl-p-tolyl-carbonat;Carbonic acid,4-methylphenyl phenyl ester;p-methylphenyl phenyl carbonate;carbonic acid phenyl ester-p-tolyl ester;p-Tolyl-phenylcarbonat;

Chemical Property of Carbonic acid phenyl p-tolyl ester

Chemical Property:

• PSA: 35.53000
• LogP: 3.57280

Purity/Quality:

99.90% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Carbonic acid phenyl p-tolyl ester

There total 6 articles about Carbonic acid phenyl p-tolyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 30.0%

dimethyl acetylenedicarboxylate (762-42-5) + 5,5-dimethyl-2-(p-methylphenoxy)-2-phenoxy-Δ3-1,3,4-oxadiazoline (351197-69-8) → p-methylphenyl phenyl carbonate (13183-20-5) + dimethyl 3,3-dimethyl-3H-pyrazole-4,5-dicarboxylate (13566-26-2) + (E)-phenylethenetricarboxylic acid 1,2-dimethyl p-methylphenyl ester + (E)-p-methylphenylethenetricarboxylic acid 1,2-dimethyl phenyl ester

Guidance literature:

In benzene; at 110 ℃; for 24h; Title compound not separated from byproducts;

DOI:10.1139/v02-012

Reference yield:

p-cresol (106-44-5) + phenyl chloroformate (1885-14-9) → p-methylphenyl phenyl carbonate (13183-20-5)

Guidance literature:

With pyridine; In chloroform;

DOI:10.1021/ja00963a021

Reference yield:

4-methylphenyl 4-nitrophenyl carbonate (439688-37-6) + phenol (108-95-2,27073-41-2) → p-methylphenyl phenyl carbonate (13183-20-5)

Guidance literature:

With potassium chloride; at 25 ℃; Further Variations:; pH-values; Kinetics;

DOI:10.1021/jo0255532

upstream raw materials:

sodium 4-methylphenoxide

phenyl chloroformate

p-cresol

4-methylphenyl 4-nitrophenyl carbonate

Downstream raw materials:

methyl (2,2,3,3-tetrafluoropropyl) carbonate

Refernces

• 1、 Lu, Xiaosong,Warkentin, John. "Ortho substituent effects on transfer of aryl groups from oxygen to carbon in adducts from diaryloxycarbenes and DMAD". . p. 228 - 234. Retrieved 2007/10/03.