Borane, chlorobis(4-methylphenyl)-

Base Information

• Chemical Name: Borane, chlorobis(4-methylphenyl)-
• CAS No.: 13272-74-7
• Molecular Formula: C14H14BCl
• Molecular Weight: 228.529
• DSSTox Substance ID: DTXSID40477676
• Mol file: 13272-74-7.mol

Synonyms:Borane, chlorobis(4-methylphenyl)-;13272-74-7;SCHEMBL8629317;DTXSID40477676

Chemical Property of Borane, chlorobis(4-methylphenyl)-

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 2
• Exact Mass: 228.0877083
• Heavy Atom Count: 16
• Complexity: 181

Purity/Quality:

98%min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: B(C1=CC=C(C=C1)C)(C2=CC=C(C=C2)C)Cl

Technology Process of Borane, chlorobis(4-methylphenyl)-

There total 4 articles about Borane, chlorobis(4-methylphenyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

bis(4-methylphenyl)dimethylstannane (1213-36-1) + boron trichloride (10294-34-5) → bis(p-tolyl)boron chloride (13272-74-7)

Guidance literature:

In n-heptane; byproducts: dimethyltin dichloride; glovebox; addn. of 1 equiv. of BCl3 as 1 M soln. in heptane to a flask contg. dimethyldiaryltin and heptane at room temp., sealing, stirring at room temp. for 30 min, heating at 100°C in oil bath for 24-48 h; cooling, decantation, removal of volatiles, recrystn. from petroleum ether at -35°C;

DOI:10.1021/ic034150x

Reference yield:

{(4-CH3-C6H4)2B}2O (96216-69-2) → bis(p-tolyl)boron chloride (13272-74-7)

Guidance literature:

With boron trichloride; In dichloromethane; at -80 ℃;

DOI:10.1016/S0022-328X(00)90824-6

Reference yield:

boron trichloride (10294-34-5) + tri(p-tolyl)bismuth (5142-75-6) → bis(p-tolyl)boron chloride (13272-74-7)

Guidance literature:

In hexane; dichloromethane; at 0 - 55 ℃; Inert atmosphere;

DOI:10.1021/acs.orglett.8b01534

upstream raw materials:

{(4-CH₃-C₆H₄)2B}2O

bis(4-methylphenyl)dimethylstannane

boron trichloride

para-methylphenylmagnesium bromide

Downstream raw materials:

(4-CH₃C₆H₄)2B-N(C₆H₅)2

(4-CH₃C₆H₄)2BNH-i-C₄H₉

(4-CH₃C₆H₄)2B-N(CH₃)2

(4-CH₃C₆H₄)2BNHC₂H₅