Boron trichloride

Base Information

• Chemical Name: Boron trichloride
• CAS No.: 10294-34-5
• Deprecated CAS: 31012-04-1
• Molecular Formula: BCl3
• Molecular Weight: 117.17
• Hs Code.: 28121049
• European Community (EC) Number: 233-658-4
• ICSC Number: 0616
• UN Number: 1741
• UNII: K748471RAG
• DSSTox Substance ID: DTXSID2041676
• Nikkaji Number: J42.058A
• Wikipedia: Boron trichloride
• Wikidata: Q415872
• Mol file: 10294-34-5.mol

Synonyms:Boronchloride (BCl3) (8CI);Trichloroborane;Trichloroboron;

Chemical Property of Boron trichloride

Chemical Property:

• Appearance/Colour: colourless gas
• Vapor Pressure: 29.72 psi ( 55 °C)
• Melting Point: -107 °C(lit.)
• Boiling Point: 12.5 °C at 760 mmHg
• Flash Point: -17 °C
• PSA: 0.00000
• Density: 1.384 g/cm³
• LogP: 1.68770
• Storage Temp.: 2-8°C
• Sensitive.: Moisture Sensitive
• Solubility.: Miscible with dichloromethane, ethanol, carbon tetrachloride, di
• Water Solubility.: decomposes
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 115.915863
• Heavy Atom Count: 4
• Complexity: 8
• Transport DOT Label: Poison Gas Corrosive

Purity/Quality:

99.9% ^*data from raw suppliers

BoronTrichloride(1MsolutioninDichloromethane) ^*data from reagent suppliers

Safty Information:

• Pictogram(s): T+, T, N, F
• Hazard Codes: T+,T,N,F
• Statements: 14-26/28-36/37/38-40-67-65-62-51/53-48/20-34-11-50/53-26/27/28-63-39/23/24/25-24-21-10
• Safety Statements: 9-26-28-36/37/39-45-8-61-38-28A-16-1-60-33-23-7/9-62-36/37

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Chemical Classes: Toxic Gases & Vapors -> Corrosive Gases
• Canonical SMILES: B(Cl)(Cl)Cl
• Inhalation Risk: A harmful concentration of this gas in the air will be reached very quickly on loss of containment.
• Effects of Short Term Exposure: The substance is corrosive to the eyes, skin and respiratory tract. Inhalation of this gas may cause lung oedema. Rapid evaporation of the liquid may cause frostbite. Exposure at high levels could cause death. The effects may be delayed. Medical observation is indicated.
• Description: Boron trichloride is a colorless, acid gas that fumes in the presence of moist air. It is packaged in steel cylinders as a liquid under its own vapor pressure of 19.1 psia (132 kPa, abs) at 70°F (21.1°C). It reacts with water or moist air to produce hydrochloric and boric acid.
• Uses: Boron trichloride is a Lewis acid, forming stable addition compounds with such donors as ammonia and the amines and is used in the laboratory to promote reactions that liberate these donors. The compound is important industrially as a source of pure boron (reduction with hydrogen) for the electronics industry. It is also used for the preparation of boranes by reaction with metal hydrides. manufacture of and purification of boron; as catalyst for organic reactions; in semiconductors; in bonding of iron, steels; in purification of metal alloys to remove oxides, nitrides and carbides. Boron trichloride is used in the refining of aluminum, copper, magnesium, and zinc to remove oxides, nitrides, and carbides trom the molten metal. Carbon monoxide, hydrogen, and nitrogen can be removed from an aluminum melt by treating with boron trichloride. It also improves the tensile strength of aluminum and will allow remelting without a major change in the grain structure. The electronic industry benefits trom boron trichloride in many applications. It is used in the production of optical fibers, as a p-type dopant for thermal diffusion in silicon, and for ion implantation.

Technology Process of Boron trichloride

There total 246 articles about Boron trichloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

aluminium trichloride (7446-70-0) + boron trifluoride (7637-07-2) → aluminum(III) fluoride (7784-18-1) + boron trichloride (10294-34-5)

Guidance literature:

heating with excess of BF3; condensation of BCl3 in an U-tube cooled the mixt. of CO2 and alcohol; fractionated distn.;

DOI:10.1021/ja01862a078

Reference yield:

boron trioxide + phosphorus pentachloride (10026-13-8,874483-75-7) → boron trichloride (10294-34-5) + trichlorophosphate (10025-87-3,12599-09-6,63736-95-8,39380-77-3)

Guidance literature:

Reference yield:

bis(trichlorosilyl)amino dichloroborane (20410-29-1) → tetrachlorosilane (10026-04-7,53609-55-5) + 1,3-bis(trichlorosilyl)-2-dichloro-4-chloro-cyclo-1,3-diaza-2-sila-4-borane (20410-32-6) + boron trichloride (10294-34-5)

Guidance literature:

at 200°C;

DOI:10.1016/0020-1650(68)80103-5

upstream raw materials:

ethyl 1,1-dichloroacetate

butoxy-dichloro-borane

dichloro(neopentyloxy)borane

(2-chloroethoxy)dichloroborane

Downstream raw materials:

bis(pentafluorophenyl)boron chloride

dimethyltin dichloride

2-chloro-1-propanol

1-Chloro-2-propanol

Refernces

• 1、 Baghlaf, A. O.,Thompson, A.. "". . p. 291 - 293. Retrieved 1977.
• 2、 Apple, E. F.,Wartik, T.. "". . p. 6153 - 6154. Retrieved 1958.
• 3、 Onak, Thomas,Dunks, Gary B.,Searcy, I. William,Spielman. "Reactions of pentaborane(9) and pentaborane derivatives". . p. 1465 - 1471. Retrieved 1967.
• 4、 Massey,Thompson. "". . p. 175. Retrieved 1963.
• 5、 Siebert et al.. "". . p. 29,32. Retrieved 1969.
• 6、 Myers, Hulon W.,Putnam, Roy F.. "On the properties of monochlorodiborane". . p. 655 - 657. Retrieved 1963.
• 7、 Myer, H. W.,Putman, R. F.. "". . p. 664 - 668. Retrieved 1962.
• 8、 Motojima,Hotta. "TiB2 COATINGS ON PHOSPHOR BRONZE PLATES BY CVD AND THEIR PROPERTIES.". . p. 327 - 333. Retrieved 1988.
• 9、 Feeney, J.,Holliday, A. K.,Marsden, F. J.. "". . . Retrieved 1961.
• 10、 Holliday, A. K.,Massey, A. G.. "". . . Retrieved 1960.